WO1999000842A1 - Substrate for mounting semiconductor chips - Google Patents
Substrate for mounting semiconductor chips Download PDFInfo
- Publication number
- WO1999000842A1 WO1999000842A1 PCT/JP1998/002872 JP9802872W WO9900842A1 WO 1999000842 A1 WO1999000842 A1 WO 1999000842A1 JP 9802872 W JP9802872 W JP 9802872W WO 9900842 A1 WO9900842 A1 WO 9900842A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- semiconductor chip
- substrate
- mounting
- boundary
- area
- Prior art date
Links
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- 239000000758 substrate Substances 0.000 title claims abstract description 121
- 239000004020 conductor Substances 0.000 claims abstract description 59
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- 239000011248 coating agent Substances 0.000 claims abstract description 23
- 238000000576 coating method Methods 0.000 claims abstract description 23
- 238000009413 insulation Methods 0.000 claims description 8
- 238000003825 pressing Methods 0.000 claims description 4
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- 229910000679 solder Inorganic materials 0.000 description 24
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 17
- 229910052802 copper Inorganic materials 0.000 description 11
- 239000010949 copper Substances 0.000 description 11
- 238000000034 method Methods 0.000 description 11
- 239000003795 chemical substances by application Substances 0.000 description 9
- 239000002245 particle Substances 0.000 description 9
- 239000004962 Polyamide-imide Substances 0.000 description 8
- 239000011889 copper foil Substances 0.000 description 8
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- CXASIZUKWKCVJC-UHFFFAOYSA-N 4-[4-[4-(4-aminophenyl)phenyl]sulfonylphenyl]aniline Chemical compound C1=CC(N)=CC=C1C1=CC=C(S(=O)(=O)C=2C=CC(=CC=2)C=2C=CC(N)=CC=2)C=C1 CXASIZUKWKCVJC-UHFFFAOYSA-N 0.000 description 1
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- 230000001746 atrial effect Effects 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- LSDYQEILXDCDTR-UHFFFAOYSA-N bis[4-(4-aminophenoxy)phenyl]methanone Chemical compound C1=CC(N)=CC=C1OC1=CC=C(C(=O)C=2C=CC(OC=3C=CC(N)=CC=3)=CC=2)C=C1 LSDYQEILXDCDTR-UHFFFAOYSA-N 0.000 description 1
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- ZZTCPWRAHWXWCH-UHFFFAOYSA-N diphenylmethanediamine Chemical compound C=1C=CC=CC=1C(N)(N)C1=CC=CC=C1 ZZTCPWRAHWXWCH-UHFFFAOYSA-N 0.000 description 1
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- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 1
- 150000002366 halogen compounds Chemical class 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 1
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- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 238000012536 packaging technology Methods 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
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- 229920002647 polyamide Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
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- 150000003335 secondary amines Chemical class 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000010944 silver (metal) Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-O sulfonium Chemical compound [SH3+] RWSOTUBLDIXVET-UHFFFAOYSA-O 0.000 description 1
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- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 1
- 125000005628 tolylene group Chemical group 0.000 description 1
- SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000013585 weight reducing agent Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L24/00—Arrangements for connecting or disconnecting semiconductor or solid-state bodies; Methods or apparatus related thereto
- H01L24/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
- H01L24/26—Layer connectors, e.g. plate connectors, solder or adhesive layers; Manufacturing methods related thereto
- H01L24/31—Structure, shape, material or disposition of the layer connectors after the connecting process
- H01L24/32—Structure, shape, material or disposition of the layer connectors after the connecting process of an individual layer connector
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/50—Assembly of semiconductor devices using processes or apparatus not provided for in a single one of the groups H01L21/18 - H01L21/326 or H10D48/04 - H10D48/07 e.g. sealing of a cap to a base of a container
- H01L21/56—Encapsulations, e.g. encapsulation layers, coatings
- H01L21/563—Encapsulation of active face of flip-chip device, e.g. underfilling or underencapsulation of flip-chip, encapsulation preform on chip or mounting substrate
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/48—Arrangements for conducting electric current to or from the solid state body in operation, e.g. leads, terminal arrangements ; Selection of materials therefor
- H01L23/488—Arrangements for conducting electric current to or from the solid state body in operation, e.g. leads, terminal arrangements ; Selection of materials therefor consisting of soldered or bonded constructions
- H01L23/498—Leads, i.e. metallisations or lead-frames on insulating substrates, e.g. chip carriers
- H01L23/49838—Geometry or layout
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/48—Arrangements for conducting electric current to or from the solid state body in operation, e.g. leads, terminal arrangements ; Selection of materials therefor
- H01L23/488—Arrangements for conducting electric current to or from the solid state body in operation, e.g. leads, terminal arrangements ; Selection of materials therefor consisting of soldered or bonded constructions
- H01L23/498—Leads, i.e. metallisations or lead-frames on insulating substrates, e.g. chip carriers
- H01L23/49866—Leads, i.e. metallisations or lead-frames on insulating substrates, e.g. chip carriers characterised by the materials
- H01L23/49894—Materials of the insulating layers or coatings
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/52—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames
- H01L23/538—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames the interconnection structure between a plurality of semiconductor chips being formed on, or in, insulating substrates
- H01L23/5386—Geometry or layout of the interconnection structure
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/30—Assembling printed circuits with electric components, e.g. with resistor
- H05K3/32—Assembling printed circuits with electric components, e.g. with resistor electrically connecting electric components or wires to printed circuits
- H05K3/321—Assembling printed circuits with electric components, e.g. with resistor electrically connecting electric components or wires to printed circuits by conductive adhesives
- H05K3/323—Assembling printed circuits with electric components, e.g. with resistor electrically connecting electric components or wires to printed circuits by conductive adhesives by applying an anisotropic conductive adhesive layer over an array of pads
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
- H01L2224/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
- H01L2224/10—Bump connectors; Manufacturing methods related thereto
- H01L2224/15—Structure, shape, material or disposition of the bump connectors after the connecting process
- H01L2224/16—Structure, shape, material or disposition of the bump connectors after the connecting process of an individual bump connector
- H01L2224/161—Disposition
- H01L2224/16151—Disposition the bump connector connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive
- H01L2224/16221—Disposition the bump connector connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked
- H01L2224/16225—Disposition the bump connector connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being non-metallic, e.g. insulating substrate with or without metallisation
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
- H01L2224/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
- H01L2224/26—Layer connectors, e.g. plate connectors, solder or adhesive layers; Manufacturing methods related thereto
- H01L2224/27—Manufacturing methods
- H01L2224/27011—Involving a permanent auxiliary member, i.e. a member which is left at least partly in the finished device, e.g. coating, dummy feature
- H01L2224/27013—Involving a permanent auxiliary member, i.e. a member which is left at least partly in the finished device, e.g. coating, dummy feature for holding or confining the layer connector, e.g. solder flow barrier
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Definitions
- the present invention relates to a semiconductor chip tower mounting substrate.
- wire bonding which has been widely used in packaging technology
- bump connection which has been widely used in packaging technology
- the latter is generally referred to as flip-chip connection, and because electrodes can be formed in an area array, it is easy to increase the number of pins, and the signal path is short and the electrical characteristics are good. Have been.
- a common flip-chip connection method uses a solder / pump placed on a wettable metal terminal of a semiconductor chip and a wettable metal terminal placed on its counterpart, and uses a riff port. First, the semiconductor chip and the substrate are electrically connected.
- An object of the present invention is to provide a substrate for mounting a semiconductor chip which is excellent in mass productivity while improving connection reliability.
- the present invention relates to a semiconductor chip mounting substrate on which a semiconductor chip having a pump is mounted with an adhesive, wherein at least a bump of the semiconductor chip is connected to a surface of the substrate in an area where the semiconductor chip is mounted.
- a wiring conductor is provided outside the region where the semiconductor chip is mounted, and the wiring conductor is exposed to the surface of the substrate near the boundary of the region where the semiconductor chip is mounted.
- the present invention provides a substrate for mounting a semiconductor chip tower, which is characterized in that there is no substrate.
- FIG. 1A is a top view showing one embodiment of the present invention
- FIG. 1B is a cross-sectional view taken along the line IB-IB of 1A.
- FIG. 2A is a top view showing another embodiment of the present invention
- FIG. 2B is a sectional view of FIG. 2A taken along the line III-III.
- FIG. 3A is a top view showing still another embodiment of the present invention
- FIG. 3B is a cross-sectional view taken along the line III-III of 3A.
- FIG. 4A is a top view showing still another embodiment of the present invention
- FIG. 4B is a sectional view taken along the line IVB-IVB of 4A.
- FIG. 5A is a top view showing a main part of Example 1 of the present invention
- FIG. 5B is a cross-sectional view of Example 1 of the present invention
- FIG. 6A is a top view showing a main part of Example 2 of the present invention
- FIG. 6B is a sectional view of Example 2 of the present invention.
- FIG. 7A is a top view illustrating a main part of a third embodiment of the present invention
- FIG. 7B is a cross-sectional view illustrating a third embodiment of the present invention.
- FIG. 8A is a top view showing a main part of Embodiment 4 of the present invention
- FIG. 8B is a cross-sectional view showing Embodiment 4 of the present invention.
- FIG. 9A is a top view illustrating a main part of a seventh embodiment of the present invention
- FIG. 9B is a cross-sectional view illustrating a seventh embodiment of the present invention.
- the substrate for mounting a semiconductor chip is a substrate for mounting a semiconductor chip on which a semiconductor chip having bumps is mounted with an adhesive, and at least a region on the surface of the substrate where the semiconductor chip is mounted. It has a connection terminal for connecting to the bump of the semiconductor chip, has a wiring conductor outside the area where the semiconductor chip is mounted, and has a wiring conductor near the boundary of the area where the semiconductor chip is mounted near the surface of the substrate. It is characterized in that it is not arranged to be exposed to
- the substrate for mounting a semiconductor chip according to the present invention is, as shown in FIGS. 1A and 1B, a substrate 8 for mounting a semiconductor chip on which a semiconductor chip 3 having a bump 4 is mounted with an adhesive 9.
- the semiconductor device has at least a connection terminal 5 for connecting to the bump 4 of the semiconductor chip 3 in a region where the semiconductor chip is mounted on the surface, and a wiring conductor 12 outside the region where the semiconductor chip is mounted.
- the wiring conductor 12 is not disposed so as to be exposed on the substrate surface near the boundary 1 of the chip mounting area.
- the semiconductor chip mounting near the boundary 1 of the area where the semiconductor chip is mounted is described.
- the wiring conductors 12 are not provided on the surface of the circuit board. In this case, the wiring conductor 12 drawn out from the connection terminal 5 only needs to be connected to the wiring conductor 122 of another conductor layer by a via hole (not shown) or a through hole 7.
- the location where the wiring conductors 12 are not located should be more than 100 zm inside and outside from boundary 1 (outline of the semiconductor chip outline) of the area where the semiconductor chip is mounted. If it is less than 10 Om, there is a possibility that the edge of the semiconductor chip 4 and the wiring conductor 12 may be shorted during mounting on a tower, which is not preferable.
- connection terminals 5 can be provided only for connection to the bumps 4 of the semiconductor chip 3 as shown in FIGS. 2A and 2B. In this case, it is only necessary to connect via holes (not shown) to through holes 7 so that connection terminals 5 are directly connected to wiring conductors 122 of another conductor layer.
- the semiconductor chip mounting substrate mounts a plurality of semiconductor chips.
- a semiconductor package multi-chip module
- a connection terminal for example, a connection terminal, an insulating layer supporting the connection terminal, a conductor on the back surface connected to the connection terminal, and a through hole connecting the connection terminal and the conductor on the back surface, the conductor being provided on the end face of the substrate
- PLCC plastic reless chip carrier
- a semiconductor package having a pad formed on the back surface of the substrate and having an arrangement interval wider than the arrangement interval of the connection terminals may be used. If solder balls are mounted on this pad, it can be used as a hole grid array (BGA), and if solder or gold bumps are formed, it can be used as a flip chip.
- BGA hole grid array
- connection terminal It also includes a connection terminal, an insulating layer supporting the connection terminal, an inner conductor connected to the connection terminal, and a via hole connecting the connection terminal and the inner conductor.
- the inner conductor is formed on an end face of the substrate. It can also be used for PLCCs that are connected to half of the through holes.
- the wiring conductor 12 As a second means for arranging the wiring conductor 12 near the boundary 1 of the region where the semiconductor chip is mounted without exposing the surface to the surface, there is the following method. That is, the wiring conductor is pulled out from the connection terminal, is provided beyond the boundary of the region where the semiconductor chip is mounted, and the insulating coating covering the wiring conductor is formed outside the region where the semiconductor chip is mounted.
- the surface of the substrate for mounting a semiconductor chip near the boundary of the area where the semiconductor chip is mounted fixes the semiconductor chip so that the wiring conductor is not exposed to the surface near the boundary of the area where the semiconductor chip is mounted. Is to be covered with an adhesive.
- the wiring conductor is drawn out from the connection terminal and provided beyond the boundary of the area where the semiconductor chip is mounted, and the wiring conductor is exposed near the boundary of the area where the semiconductor chip is mounted so that the wiring conductor is not exposed. Insulating coating to cover the semiconductor chip To cover the wiring conductor at the boundary of the area to be covered, and also to cover the outside of the area where the semiconductor chip is mounted.
- the second means of the present invention is that, due to the downsizing of the semiconductor tower mounting board, the above means cannot be taken unavoidably, and the wiring conductor drawn out from the connection terminal is connected to the boundary of the area where the semiconductor chip is mounted. It is possible to deal with the case where it needs to be established beyond the limit.
- the second means for preventing the wiring conductor 12 from being exposed and arranged near the boundary 1 of the area where the semiconductor chip is mounted is, as shown in FIGS. 3A and 3B, an insulating covering the wiring conductor 1.
- the coating 6 is formed outside the region where the semiconductor chip is mounted, and the surface of the semiconductor mounting substrate near the boundary 1 of the region where the semiconductor chip is mounted is bonded with an adhesive for fixing the semiconductor chip. Is to be covered by
- the boundary 2 of the insulating coating is in a range from the boundary 1 of the region where the semiconductor chip is mounted to 300 ⁇ m outward. If it exceeds 300 ⁇ m, the wiring conductors 12 cannot be completely covered with the adhesive 9, which causes a reduction in insulation reliability.
- the insulating coating 6 is preferably made of a material commonly used for a solder resist, and can also be formed by application by silk screen printing or lamination of a film or sheet insulating material.
- solder resist ink has low material cost and is suitable for mass production.
- the thickness of the insulating coating 6 is preferably 15 to 50 ⁇ m. If it is less than 15 m, it is difficult to form an insulating film uniformly, and if it exceeds 50 / zm, insulation reliability will be good, but a thickness exceeding 50 m will be formed. Requires multiple applications of resin, which reduces mass productivity and raises costs.
- the insulating coating 6 is 20 to 20 times wider than the boundary 1 of the region where the semiconductor chip is mounted. Preferably, it is formed up to a depth of 300 m. If it is less than 200 m, the wiring may not be covered due to the displacement of the solder resist, and the area may be directly below the outer periphery of the semiconductor chip, causing a short circuit at the time of mounting. Insulation coating is formed up to the vicinity of the connection terminal 5, and the connection reliability may be reduced due to contamination of the surface of the connection terminal 5.
- the film thickness of the insulating coating 6 must be a gap between the semiconductor chip 3 and the insulating coating 6. It is preferable that the setting is made such that When the semiconductor chip 3 is heated and pressurized and connected to the semiconductor chip mounting substrate 8, the adhesive 9 can flow through the gap, so that no pressure is applied to other parts and no stress remains. And less deformation after connection.
- the insulating coating 6 can prevent most of the adhesive 9 from flowing out and allow a part of the adhesive 9 to flow outward from the boundary of the insulating coating. Therefore, no pressure is applied to other parts and no stress remains, so that the deformation after connection is small, and the resilience is also reduced by the wiring conductors 12 existing in and near the area where the semiconductor chip is mounted, The space between the semiconductor chip and the back surface is sealed and protected by shielding it from air.
- FIGS. 5A and 5B and FIGS. 6A and 6B a first method for preventing the wiring conductors 12 from being exposed and arranged near the boundary 1 of the area where the semiconductor chip is mounted is shown. The same effect can be obtained by using the method together with the means.
- connection terminal 5 is supported by a substrate reinforced with a glass cloth.
- the semiconductor tower mounting substrate on which the connection terminal 5 is supported is a substrate provided with a build-up layer on a substrate reinforced with glass cloth, and the connection terminal 5 is directly supported by the build-up layer.
- a build-up layer may be an insulating layer reinforced with a glass nonwoven fabric, or may be an insulating layer reinforced with an aramide fiber.
- Examples of the resin composition used for the adhesive for bonding the semiconductor chip mounting substrate and the semiconductor chip having bumps according to the present invention include an epoxy resin and an imidazole-based, hydrazide-based, boron trifluoride-amine complex, and sulfonium.
- a mixture of latent hardeners such as salt, amine imide, salt of polyamide, dicyan diamide, etc.
- an adhesive resin composition having a storage elastic modulus at 40 ° C. of 100 to 150 MPa after bonding is preferable.
- epoxy resin and imidazole-based, hydrazide-based, boron trifluoride-amine complex, sulfonium salt, amide imide, and epoxy resin as adhesive resin compositions capable of obtaining good fluidity and high connection reliability at the time of connection.
- the storage elastic modulus at 40 ° C after adhesion to a mixture of latent curing agents such as polyamine salts and dicyandiamide is 100 to 150 M
- An adhesive in which acryl rubber is blended so as to obtain Pa is used.
- the elastic modulus is, for example, Rheoztra DVE- manufactured by Rheology Co., Ltd.
- Examples of the acryl rubber to be mixed with the adhesive include polymers or copolymers containing at least one of atrial acid, acrylate, methacrylate or acrylonitrile as a monomer component. Among them, a copolymer acrylic rubber containing glycidyl acrylate / glycidyl methacrylate containing a glycidyl ether group is preferably used.
- the molecular weight of these acrylic rubbers is preferably 200,000 or more from the viewpoint of increasing the cohesive strength of the adhesive. If the amount of the acrylic rubber in the adhesive is less than 15 wt%, the storage elastic modulus at 40 ° C after bonding exceeds 150 OMPa, and if it exceeds 40 wt%, Although the modulus of elasticity can be reduced, the melt viscosity at the time of connection increases, and the exclusion of the molten adhesive at the interface between the connection electrodes or the interface between the connection electrode and the conductive particles decreases. Since it becomes impossible to secure electrical conduction between them, the amount of acryl is preferably 15 to 40 wt%.
- thermoplastic resin such as a phenoxy resin
- the phenoquine resin is preferable because it has a similar structure to the epoxy resin, and has characteristics such as excellent compatibility and adhesion with the epoxy resin.
- an adhesive composition consisting of rubber, phenoxy resin, and a latent curing agent is dissolved or dispersed in an organic solvent, liquefied, applied to a peelable substrate, and the solvent is removed at a temperature lower than the activation temperature of the curing agent.
- a mixed solvent of an aromatic hydrocarbon type and an oxygen-containing type is preferable since the solubility of the material is improved.
- Conductive particles can also be dispersed in this adhesive for the purpose of positively imparting anisotropic conductivity in order to absorb variations in height of bumps and circuit electrodes of a semiconductor chip.
- Such conductive particles are, for example, metal particles such as Au, Ni, Ag, Cu, W, and solder, or a metal formed by depositing or depositing a thin film such as gold or palladium on the surface of these metal particles. It is a particle, and a conductive particle in which a conductive layer of Ni, Cu, Au, solder, or the like is provided on a spherical core material of a polymer such as polystyrene can be used.
- the particle size must be smaller than the minimum distance between the electrodes on the substrate, and if there is variation in the height of the electrodes, it is preferably larger than the variation, and the range of l ⁇ m to 10 ⁇ m is preferred. .
- the amount of the conductive particles dispersed in the adhesive is 0.1 to 30% by volume, and preferably 0.1 to 20% by volume.
- a commercially available example of such an anisotropic conductive adhesive is Flip Tack (trade name, manufactured by Hitachi Danisei Kogyo Co., Ltd.).
- the resin used to fill the through holes with a resin is preferably a resin composition comprising a polyamideimide resin and a thermosetting component.
- polyamide imide resin examples include an aromatic polyamide amide obtained by reacting an aromatic diimide carboxylic acid obtained by reacting a diamine having three or more aromatic rings with anhydrous trimetic acid and an aromatic diisocyanate.
- aromatic polyamideimide resin obtained by reacting 4,4′-diphenylmethanediisocyanate.
- Diamines having three or more aromatic rings include 2,2-bis [4- (4-aminoaminophenoxy) phenyl] propane and bis [4-1- (3-aminophenoxy) phenyl. Nyl] sulfone, bis [4- (4-aminophenyl) phenyl] sulfone, 2,2-bis [4- (4-aminophenyl) phenyl] hexafluoropropane, bis [4- (4-aminophenyl) phenyl] Methane, 4,4-bis (4-aminophenoxy) biphenyl, bis [4- (4-aminophenoxy) phenyl] ether, bis [4- (4-aminophenyloxy) phenyl] ketone, 1,3-bi (4-aminophenoxy) benzene, 1,4-bis (4-aminophenoxy) benzene, etc. can be used alone or in combination.
- Aromatic diisocyanates include 4,4'-diphenylmethane diisocyanate, 2,4-tolylene diisocyanate, 2,6-tolylene diisocyanate, naphthalene-1,5-diisocyanate, , 4 _ tolylene dimer and the like can be used alone or in combination.
- thermosetting component is preferably an epoxy resin and a curing agent or a curing accelerator thereof, and the epoxy resin may be any one having at least two glycidyl groups. More preferably, the number of glycidyl groups is three or more.
- the epoxy resin may be liquid or solid at room temperature.
- Commercially available liquid epoxy resins include bisphenol A type, such as YD128, YD812 (trade name, manufactured by Tohto Kasei Kogyo Co., Ltd.), and the like. (Trade name, manufactured by Yuka Shiyeloxy Co., Ltd.), DER333 (trade name, manufactured by Dow Chemical Industry Co., Ltd.), etc. Bisphenol F type, YDF170, YDF204, etc.
- Examples of the solid epoxy resin include YD90 7. YDCN704S, YDPN172 (all manufactured by Toto Kasei Kogyo Co., Ltd., trade names), etc. Ep180 S70 (made by Yuka Shell Epoxy Co., Ltd., trade name), etc., ESA019, ESCN195 (made by Sumitomo Chemical Co., Ltd., trade name), etc., DER666, DEN43 8 (manufactured by Dow Chemical Industry Co., Ltd., trade name), and EOCN 102 (manufactured by Nippon Kayaku Co., Ltd., trade name).
- a brominated epoxy resin may be used.
- commercially available products such as YDB400 (trade name, manufactured by Toto Kasei Kogyo Co., Ltd.), Ep 505 0 (manufactured by Yuka Shell Epoxy Co., Ltd.), etc. Manufactured by Tomo Chemical Industry Co., Ltd.).
- amines As the curing agent or curing accelerator for the epoxy resin, amines, imidazoles, polyfunctional phenols, acid anhydrides, isocyanates and the like can be used.
- Examples of amines include dicyandiamide, diaminodiphenylmethane, guanyl urea, and the like.
- Examples of imidazoles include alkyl-substituted imidazole and benzimidazole, and examples of polyfunctional phenols include hydroquinone, resorcinol, and bisphenol A. And its halogen compounds, as well as condensates with aldehydes, such as novolak and resole resins.
- Examples of acid anhydrides include anhydrous hydrofluoric acid, hexahydrohydroanhydride, and benzophenone tetra. There are carboxylic acids and the like.
- Examples of the isocyanates include tolylene diisocyanate and isophorone diisocyanate. Those obtained by masking this isocyanate with phenols or the like may be used.
- the necessary amount of these curing agents is preferably such that the active hydrogen equivalent of the amine and the epoxy equivalent of the epoxy resin are substantially equal.
- the active hydrogen equivalent of the amine and the epoxy equivalent of the epoxy resin are substantially equal.
- isocyanates react with both the polyamide imide resin and the epoxy resin, so that 0.8 to 2 equivalents are required for 1 equivalent of each.
- curing agents or curing accelerators may be used alone, but if necessary, a plurality of curing agents or curing accelerators may be selected.
- the weight ratio of the polyamide imide resin to the thermosetting component may be in the range of 10 to 150 parts by weight of the thermosetting component to 100 parts by weight of the polyamide imide resin.
- the amount is less than 10 parts by weight, the line from the glass transition point to 350 ° C.
- Polyamide imide resin has a large expansion coefficient and low storage elastic modulus at 300 ° C. If it exceeds 150 parts by weight, the compatibility decreases and gelation occurs during stirring. .
- MCL-E-67 (trade name, manufactured by Hitachi Chemical Co., Ltd.), which is a 0.8-mm thick double-sided copper-clad laminate with 18-zm copper foil laminated on both sides as a support for the substrate, Drill a hole to become through hole 7 in B, and immerse it in L_59 plating solution (trade name, manufactured by Hitachi Chemical Co., Ltd.), which is an electroless copper plating solution, at a solution temperature of 70 ° C for 8 hours. 5 ⁇ m of plated copper was deposited. Thereafter, unnecessary copper was selectively removed by etching to form a wiring conductor 122, and the through-hole 7 was filled with resin. At this time, the resin filled in the through holes 7 was prepared as follows.
- GEA-679 NP (trade name, manufactured by Hitachi Chemical Co., Ltd.), a 50-m-thick epoxy resin pre-predeer reinforced with glass nonwoven fabric, was used. And 18 m copper foil in this order, heat and press at 170 ° C and 2.5 MPa, 90 min, and etch away only the copper foil at via hole 71 Then, a laser beam was applied to the location, a hole was reached to reach the wiring conductors 122, and the electroless plating solution L-59 plating solution (Hitachi Chemical Co., Ltd., trade name) was added to the solution temperature.
- the semiconductor chip mounting substrate 8 is formed such that the opening 21 of the solder resist 61 is the same as the outer shape 101 of the semiconductor chip or the outer shape 101 of the semiconductor chip. Are also large.
- bumps 4 are formed on the terminal electrodes of the semiconductor chip 3 by plating, and a flip-tack (a product of Hitachi Chemical Co., Ltd. Is positioned between the semiconductor chip mounting substrate 8 and the semiconductor chip 3, and the semiconductor chip 3 is oriented downward to the connection terminal 5 on the semiconductor chip mounting substrate 8, and the semiconductor After mounting the semiconductor chip on the chip tower mounting substrate 8, the bump 4 of the semiconductor chip 3 is heated and pressed from above the chip under the conditions of 180 ° C, 30 g / bump, and 20 seconds.
- the connection terminals 5 of the semiconductor chip mounting substrate 8 were electrically connected via an anisotropic conductive adhesive 91.
- the semiconductor chip 3 and the substrate 8 for mounting a semiconductor chip can be connected in a very simple, stable, powerful, and versatile manner. Further, any defective solder-resist 61 formed on the chip mounting surface of the semiconductor chip mounting substrate 8 is The connection reliability after mounting three semiconductor chips was good.
- the solder heat resistance of the through-holes was such that even if the through-holes were floated at 260 ° C. for 1 minute, no through-hole voids were generated and no detachment from the base resin was observed.
- a semiconductor chip mounting substrate 8 was prepared in the same manner as in Example 1, and as shown in FIG. 6A, the opening 21 of the solder resist 61 was formed smaller than the outer shape 101 of the semiconductor chip 3. did.
- the tip of the gold wire is melted on a terminal electrode of the semiconductor chip 3 with a torch or the like to form a gold ball, and the ball is pressed onto the electrode pad.
- a bump 4 obtained by cutting is provided, and a flip-tack (trade name, manufactured by Hitachi Chemical Co., Ltd.) which is an anisotropic conductive adhesive 91 is applied between the semiconductor chip tower mounting substrate 8 and the semiconductor chip 3. After the semiconductor chip 3 is turned downward, the semiconductor chip 3 is positioned on the connection terminal 5 on the semiconductor chip tower substrate 8, and the semiconductor chip 3 is mounted on the semiconductor chip tower substrate 8.
- the bumps 4 of the semiconductor chip 3 and the connection terminals 5 of the semiconductor chip mounting substrate 8 are heated and pressurized from above the chip under the conditions of 180 ° C, 30 bumps, and 20 seconds to form a conductive adhesive. Connected electrically via 9 1.
- the semiconductor chip 3 and the substrate 8 for mounting a semiconductor chip on the semiconductor chip can be connected in a very simple, stable, and versatile manner. Furthermore, there was no defective formation of the solder resist 61 formed on the chip mounting surface of the semiconductor chip mounting substrate 8, and the connection reliability after mounting the semiconductor chip was good.
- the through-hole solder heat resistance was such that even when the through-hole was floated for one minute in molten solder at 260 ° C., no through-hole voids were generated and no detachment from the base resin was observed.
- a semiconductor chip mounting substrate 8 was prepared in the same manner as in Example 1, and as shown in FIG. 7A, the wiring conductors 12 formed on the surface of the semiconductor chip mounting substrate 8 correspond to the outer shape 1 of the chip. No opening was formed below, and the opening 21 of the solder resist 61 was formed 100 m larger than the outline 101 of the semiconductor chip 3.
- the terminal electrodes of the semiconductor chip 3 are bumped by plating. 4 is formed, and a flip-tack (trade name, manufactured by Hitachi Chemical Co., Ltd.) is disposed between the semiconductor chip mounting substrate 8 and the semiconductor chip 3 as an anisotropic conductive adhesive 91.
- a flip-tack (trade name, manufactured by Hitachi Chemical Co., Ltd.) is disposed between the semiconductor chip mounting substrate 8 and the semiconductor chip 3 as an anisotropic conductive adhesive 91.
- the bumps 4 of the semiconductor chip 3 and the connection terminals 5 of the semiconductor chip mounting substrate 8 are heated and pressed from above the chip under the conditions of 0 g / bump for 20 seconds to connect the connection terminal 5 of the semiconductor chip 3 with the anisotropic conductive adhesive 91. Connected electrically.
- the semiconductor chip 3 and the substrate 8 for mounting the semiconductor chip could be connected in a very simple, stable, powerful, and versatile manner. Further, there was no defective formation of the solder resist 61 formed on the chip mounting surface of the semiconductor chip mounting substrate 8, and the connection reliability after mounting the semiconductor chip was good.
- the solder heat resistance of the through-holes was such that even when the through-holes were floated at 260 ° C. for 1 minute, no through-hole voids were generated and no detachment from the base resin was observed.
- MCL—E—6979 a single-sided copper-clad laminate consisting of a single-sided copper-clad laminate with a thickness of 0.8 mm and 18-millimeter copper foil on one side as the semiconductor chip mounting substrate 8 (manufactured by Hitachi Chemical The product was prepared by removing unnecessary portions of copper by etching.
- the opening 21 of the solder resist 61 was formed 150 m larger than the outline 101 of the semiconductor chip 3 on the substrate 8 for mounting a semiconductor chip.
- bumps 4 are formed on the terminals of the semiconductor chip 3 by plating, and a flip-tack (trade name, manufactured by Hitachi Chemical Co., Ltd.) which is an anisotropic conductive adhesive 91 is applied.
- the semiconductor chip 3 is disposed between the semiconductor chip mounting substrate 8 and the semiconductor chip 3, and the bumps 4 are aligned with the connection terminals 5 on the semiconductor chip mounting substrate 8 with the semiconductor chip 3 facing downward.
- the bumps 4 of the semiconductor chip 3 and the connection terminals 5 of the semiconductor chip tower mounting substrate 8 are heated and pressed from above the chip at 180 ° C, 30 g / bump, and 20 seconds.
- the semiconductor chip mounting substrate 8 is a 50-mm-thick epoxy resin prepreg reinforced with a glass nonwoven fabric, GEA—679 NP ( Hitachi Chemical Industry Co., Ltd., trade name) and an 18 m copper foil in this order were used for the inner layer circuit board manufactured by the same method using the same material as the semiconductor chip mounting substrate 8 used in Example 4. Laminated on top, heated and pressurized at 170 ° C under 2.5 MPa, 90 minutes, and after laminating and integrating, only the copper foil at the location that became via hole 71 was removed by etching.
- GEA—679 NP Hitachi Chemical Industry Co., Ltd., trade name
- a semiconductor tower was mounted in the same manner as in Example 5, except that EA-541 (product name, manufactured by Shin-Kobe Electric Co., Ltd.), an epoxy resin pre-preda reinforced with aramide fiber, was used for the build-up layer 81.
- a semiconductor chip 3 was mounted on the semiconductor chip mounting substrate 8 in the same manner as in Example 5.
- the bonding agent flows when heated and pressurized, so that the generation of voids can be suppressed and the resin can be sealed with resin. Since the insulation between the connection portions is sufficiently maintained, the connection reliability between the semiconductor chip connection terminals and the connection terminals of the semiconductor mounting substrate is high. Since the connecting step between the semiconductor chip 3 and the semiconductor chip mounting substrate 8 and the resin sealing step between the semiconductor chip 3 and the semiconductor chip mounting substrate 8 can be performed simultaneously, the mounting step Also has excellent mass productivity.
- the opening 2 of the solder resist 6 1 is stronger than the semiconductor chip 3, except for an adhesive sufficient for sealing, it can escape to the outside, the residual stress in the connection process is small, and it is difficult to deform. .
- the reliability of the connection can be improved by heating and pressing.
- MCL—E—679 (a single-sided copper-clad laminate with a 0.8-mm-thick copper foil bonded to one side as a substrate for mounting semiconductor chips on a single-sided board) (manufactured by Hitachi Chemical Co., Ltd.) The product was prepared by etching and removing unnecessary portions of copper.
- an opening 21 of the solder-resist 61 was formed in the substrate 8 for mounting a semiconductor chip on the substrate 8 by 150 zm smaller than the outline 1 of the semiconductor chip 3.
- bumps 4 are formed on the terminals of the semiconductor chip 3 by plating, and a flip-tack (trade name, manufactured by Hitachi Chemical Co., Ltd.) which is an anisotropic conductive adhesive 91 is applied.
- the semiconductor chip 3 is disposed between the semiconductor chip mounting substrate 8 and the semiconductor chip 3, and the bumps 4 are aligned with the connection terminals 5 on the semiconductor chip mounting substrate 8 with the semiconductor chip 3 facing downward.
- connection terminal 5 between the bump 4 of the semiconductor chip 3 and the substrate 8 for mounting the semiconductor chip tower 8 is anisotropically conductive. It was electrically connected via the conductive adhesive 91. As described above, it was possible to connect the semiconductor chip 3 and the semiconductor chip mounting substrate 8 in a very simple and stable manner with force, power, and versatility. Further, there was no defective formation of the solder resist 61 formed on the chip mounting surface of the semiconductor chip mounting substrate, and the connection reliability after mounting the semiconductor chip was good.
- GEA-67 a 50-meter-thick epoxy resin prepreg, which is applied to the semiconductor chip mounting substrate as a build-up layer 81 shown in Fig. 9 NP (trade name, manufactured by Hitachi Chemical Co., Ltd.) and 18 mm copper foil were manufactured in this order using the same material and the same method as the substrate for mounting the semiconductor chip 9 used in Example 7.
- EAA-541 a trade name of Shin-Kobe Electric Co., Ltd.
- an epoxy resin prepreg reinforced with aramide fiber was used for the build-up layer 81.
- the semiconductor chip 3 was mounted on the semiconductor chip mounting substrate 8 in the same manner as in Example 8.
- the opening 21 of the solder resist 6 1 is strong, and it is only necessary to form one for each semiconductor chip. Excellent mass productivity because it can be manufactured with
- the adhesive flows when heated and pressurized, the generation of voids is suppressed, and the opening 2 of the solder resist 6 1 is formed. Since 1 is smaller than the size of the semiconductor chip 3, it does not flow much except around the area where the bumps 4 of the semiconductor chip 3 and the connection terminals 5 of the substrate 8 for mounting a semiconductor chip are connected, and can be sealed with resin. Since the insulation between the connection portions is sufficiently maintained, the connection reliability between the connection terminals of the semiconductor chip 3 and the connection terminals 5 of the semiconductor chip mounting substrate 8 is high.
- the adhesive other than the adhesive sufficient for sealing can escape to the outside, and the residual stress in the connection process is small, so that it is not easily deformed.
- the reliability of the connection can be improved by heating and pressing.
- the substrate for mounting a semiconductor chip according to the present invention has improved connection reliability and excellent mass productivity. It can greatly contribute to the semiconductor chip industry because it can be manufactured in a semiconductor device.
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- Microelectronics & Electronic Packaging (AREA)
- Physics & Mathematics (AREA)
- Computer Hardware Design (AREA)
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- Condensed Matter Physics & Semiconductors (AREA)
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Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP98929711A EP0993039B1 (en) | 1997-06-26 | 1998-06-26 | Substrate for mounting semiconductor chips |
DE69835747T DE69835747T2 (de) | 1997-06-26 | 1998-06-26 | Substrat zur montage von halbleiterchips |
US09/446,674 US6281450B1 (en) | 1997-06-26 | 1998-06-26 | Substrate for mounting semiconductor chips |
Applications Claiming Priority (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP16934197A JPH1117046A (ja) | 1997-06-26 | 1997-06-26 | 半導体チップ搭載用基板 |
JP9/169341 | 1997-06-26 | ||
JP16933997A JP4058773B2 (ja) | 1997-06-26 | 1997-06-26 | 半導体チップ搭載用基板 |
JP9/169339 | 1997-06-26 | ||
JP16934097A JPH1117045A (ja) | 1997-06-26 | 1997-06-26 | 半導体チップ搭載用基板 |
JP9/169340 | 1997-06-26 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1999000842A1 true WO1999000842A1 (en) | 1999-01-07 |
Family
ID=27323160
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP1998/002872 WO1999000842A1 (en) | 1997-06-26 | 1998-06-26 | Substrate for mounting semiconductor chips |
Country Status (4)
Country | Link |
---|---|
US (1) | US6281450B1 (ja) |
EP (1) | EP0993039B1 (ja) |
DE (1) | DE69835747T2 (ja) |
WO (1) | WO1999000842A1 (ja) |
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Also Published As
Publication number | Publication date |
---|---|
EP0993039A4 (en) | 2001-02-28 |
EP0993039A1 (en) | 2000-04-12 |
US6281450B1 (en) | 2001-08-28 |
DE69835747D1 (de) | 2006-10-12 |
EP0993039B1 (en) | 2006-08-30 |
DE69835747T2 (de) | 2007-09-13 |
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