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WO2003008364A1 - Fluorination process - Google Patents

Fluorination process Download PDF

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Publication number
WO2003008364A1
WO2003008364A1 PCT/JP2002/006762 JP0206762W WO03008364A1 WO 2003008364 A1 WO2003008364 A1 WO 2003008364A1 JP 0206762 W JP0206762 W JP 0206762W WO 03008364 A1 WO03008364 A1 WO 03008364A1
Authority
WO
WIPO (PCT)
Prior art keywords
carbon dioxide
liquid
fluorination
fluoroalkane
general formula
Prior art date
Application number
PCT/JP2002/006762
Other languages
French (fr)
Japanese (ja)
Inventor
Yutaka Ohhira
Kenji Adachi
Original Assignee
Daikin Industries Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Daikin Industries Ltd. filed Critical Daikin Industries Ltd.
Priority to JP2003513925A priority Critical patent/JPWO2003008364A1/en
Publication of WO2003008364A1 publication Critical patent/WO2003008364A1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B39/00—Halogenation
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/54—Improvements relating to the production of bulk chemicals using solvents, e.g. supercritical solvents or ionic liquids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

A fluorination process which comprises fluorinating an organic compound with an electrophilic fluorinating agent bearing an N-F bond in liquid carbon dioxide, supercritical carbon dioxide, liquid fluoroalkane, or supercritical fluoroalkane; and use of quaternary-nitrogen onium salts represented by the general formula (I), specifically by the general formula (II) in the above fluorination process as the electrophilic fluorinating agent: (I) (II) (wherein X- is a conjugate base of a Brensted acid). The above process makes it possible to conduct fluorination in a liquid medium such as liquid carbon dioxide easily and safely in high yield.
PCT/JP2002/006762 2001-07-13 2002-07-03 Fluorination process WO2003008364A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2003513925A JPWO2003008364A1 (en) 2001-07-13 2002-07-03 Fluorination method

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2001213310 2001-07-13
JP2001-213310 2001-07-13

Publications (1)

Publication Number Publication Date
WO2003008364A1 true WO2003008364A1 (en) 2003-01-30

Family

ID=19048307

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2002/006762 WO2003008364A1 (en) 2001-07-13 2002-07-03 Fluorination process

Country Status (2)

Country Link
JP (1) JPWO2003008364A1 (en)
WO (1) WO2003008364A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101693648A (en) * 2009-10-16 2010-04-14 南开大学 Preparation method of 1, 7, 8- trifluoro-2- naphthol and derivative thereof
CN117247368A (en) * 2023-11-20 2023-12-19 上海如鲲新材料股份有限公司 A kind of preparation method of trans-difluoroethylene carbonate compounds

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0204535A1 (en) * 1985-06-03 1986-12-10 Sagami Chemical Research Center N-fluoropyridinium salt and process for preparing same
EP0992494A1 (en) * 1998-09-29 2000-04-12 Air Products And Chemicals, Inc. Package for safe storage of electrophilic fluorinating agent
WO2000068170A1 (en) * 1999-05-07 2000-11-16 The University Of North Carolina At Chapel Hill Fluorination in liquid or supercritical carbon dioxide

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS606339B2 (en) * 1979-04-28 1985-02-18 ダイキン工業株式会社 Fluorination method
JPH0233707B2 (en) * 1985-06-03 1990-07-30 Sagami Chuo Kagaku Kenkyusho NNFURUOROPIRIJINIUMUENOYOBISONOSEIZOHOHO
JPS62207229A (en) * 1986-03-07 1987-09-11 Sagami Chem Res Center Productin of aromatic fluorine compound
US5116982A (en) * 1990-08-06 1992-05-26 Dowelanco Preparation of fluorohalophenols and n-acyfluorohaloanilines
JP3598327B2 (en) * 1994-03-10 2004-12-08 東ソ−・エフテック株式会社 Method for producing aromatic fluorine compound
JP2001270849A (en) * 2000-03-24 2001-10-02 Daikin Ind Ltd Bis (3-fluoro-4-hydroxy-5-nitrophenyl) fluoroalkane, method for producing the same, and method for producing a synthetic intermediate thereof
EP1304316B1 (en) * 2000-06-13 2011-08-10 Daikin Industries, Ltd. Processes for the production of fluorinated organic compounds and fluorinating agents
JP2002030012A (en) * 2000-07-14 2002-01-29 Daikin Ind Ltd Method for producing fluorine compound and method for recovering or regenerating fluorinating agent precursor

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0204535A1 (en) * 1985-06-03 1986-12-10 Sagami Chemical Research Center N-fluoropyridinium salt and process for preparing same
EP0992494A1 (en) * 1998-09-29 2000-04-12 Air Products And Chemicals, Inc. Package for safe storage of electrophilic fluorinating agent
WO2000068170A1 (en) * 1999-05-07 2000-11-16 The University Of North Carolina At Chapel Hill Fluorination in liquid or supercritical carbon dioxide

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101693648A (en) * 2009-10-16 2010-04-14 南开大学 Preparation method of 1, 7, 8- trifluoro-2- naphthol and derivative thereof
CN101693648B (en) * 2009-10-16 2014-03-19 南开大学 Preparation method of 1, 7, 8- trifluoro-2- naphthol and derivative thereof
CN117247368A (en) * 2023-11-20 2023-12-19 上海如鲲新材料股份有限公司 A kind of preparation method of trans-difluoroethylene carbonate compounds
CN117247368B (en) * 2023-11-20 2024-03-19 上海如鲲新材料股份有限公司 A kind of preparation method of trans-difluoroethylene carbonate compounds

Also Published As

Publication number Publication date
JPWO2003008364A1 (en) 2004-11-04

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