WO2003008364A1 - Procédé de fluoration - Google Patents
Procédé de fluoration Download PDFInfo
- Publication number
- WO2003008364A1 WO2003008364A1 PCT/JP2002/006762 JP0206762W WO03008364A1 WO 2003008364 A1 WO2003008364 A1 WO 2003008364A1 JP 0206762 W JP0206762 W JP 0206762W WO 03008364 A1 WO03008364 A1 WO 03008364A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- carbon dioxide
- liquid
- fluorination
- fluoroalkane
- general formula
- Prior art date
Links
- 238000003682 fluorination reaction Methods 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract 6
- 239000007788 liquid Substances 0.000 abstract 4
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract 3
- 239000001569 carbon dioxide Substances 0.000 abstract 3
- 239000012025 fluorinating agent Substances 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 1
- 150000002894 organic compounds Chemical class 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B39/00—Halogenation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/54—Improvements relating to the production of bulk chemicals using solvents, e.g. supercritical solvents or ionic liquids
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
L'invention concerne un procédé de fluoration consistant à fluorer un composé organique au moyen d'un agent de fluoration électrophile porteur d'une liaison N-F dans du dioxyde de carbone liquide, du dioxyde de carbone supercritique, du fluoroalcane liquide ou du fluoroalcane supercritique ; et à utiliser comme agent de fluoration électrophile des sels onium d'azote quaternaire représentés par la formule générale (I), surtout par la formule générale (II), dans le procédé de fluoration susmentionné: (I) (II) (dans lesquelles X- désigne une base de conjugué d'un acide de Bronsted). Le procédé susmentionné permet d'effectuer facilement, de manière sûre et avec des rendements élevés, une fluoration dans un support liquide, tel qu'un dioxyde de carbone liquide.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2003513925A JPWO2003008364A1 (ja) | 2001-07-13 | 2002-07-03 | フッ素化方法 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2001213310 | 2001-07-13 | ||
JP2001-213310 | 2001-07-13 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2003008364A1 true WO2003008364A1 (fr) | 2003-01-30 |
Family
ID=19048307
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2002/006762 WO2003008364A1 (fr) | 2001-07-13 | 2002-07-03 | Procédé de fluoration |
Country Status (2)
Country | Link |
---|---|
JP (1) | JPWO2003008364A1 (fr) |
WO (1) | WO2003008364A1 (fr) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101693648A (zh) * | 2009-10-16 | 2010-04-14 | 南开大学 | 1,7,8-三氟-2-萘酚及其衍生物的制备方法 |
CN117247368A (zh) * | 2023-11-20 | 2023-12-19 | 上海如鲲新材料股份有限公司 | 一种反式二氟代碳酸乙烯酯类化合物的制备方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0204535A1 (fr) * | 1985-06-03 | 1986-12-10 | Sagami Chemical Research Center | Sel de N-fluoropyridinium et procédé pour sa préparation |
EP0992494A1 (fr) * | 1998-09-29 | 2000-04-12 | Air Products And Chemicals, Inc. | Emballage de stockage sûr d'agents de fluoration électrophiles |
WO2000068170A1 (fr) * | 1999-05-07 | 2000-11-16 | The University Of North Carolina At Chapel Hill | Fluoration de dioxyde de carbone liquide ou supercritique |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS606339B2 (ja) * | 1979-04-28 | 1985-02-18 | ダイキン工業株式会社 | フツ素化方法 |
JPH0233707B2 (ja) * | 1985-06-03 | 1990-07-30 | Sagami Chuo Kagaku Kenkyusho | Nnfuruoropirijiniumuenoyobisonoseizohoho |
JPS62207229A (ja) * | 1986-03-07 | 1987-09-11 | Sagami Chem Res Center | 芳香族フツ素化合物の製法 |
US5116982A (en) * | 1990-08-06 | 1992-05-26 | Dowelanco | Preparation of fluorohalophenols and n-acyfluorohaloanilines |
JP3598327B2 (ja) * | 1994-03-10 | 2004-12-08 | 東ソ−・エフテック株式会社 | 芳香族フッ素化合物の製造方法 |
JP2001270849A (ja) * | 2000-03-24 | 2001-10-02 | Daikin Ind Ltd | ビス(3−フルオロ−4−ヒドロキシ−5−ニトロフェニル)フルオロアルカン及びその製造方法、並びにその合成中間体の製造方法 |
EP1304316B1 (fr) * | 2000-06-13 | 2011-08-10 | Daikin Industries, Ltd. | Procedes pour la production de composes organiques fluores et agents de fluoration |
JP2002030012A (ja) * | 2000-07-14 | 2002-01-29 | Daikin Ind Ltd | フッ素化合物の製造方法、及びフッ素化剤前駆体の回収又は再生方法 |
-
2002
- 2002-07-03 JP JP2003513925A patent/JPWO2003008364A1/ja active Pending
- 2002-07-03 WO PCT/JP2002/006762 patent/WO2003008364A1/fr active Application Filing
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0204535A1 (fr) * | 1985-06-03 | 1986-12-10 | Sagami Chemical Research Center | Sel de N-fluoropyridinium et procédé pour sa préparation |
EP0992494A1 (fr) * | 1998-09-29 | 2000-04-12 | Air Products And Chemicals, Inc. | Emballage de stockage sûr d'agents de fluoration électrophiles |
WO2000068170A1 (fr) * | 1999-05-07 | 2000-11-16 | The University Of North Carolina At Chapel Hill | Fluoration de dioxyde de carbone liquide ou supercritique |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101693648A (zh) * | 2009-10-16 | 2010-04-14 | 南开大学 | 1,7,8-三氟-2-萘酚及其衍生物的制备方法 |
CN101693648B (zh) * | 2009-10-16 | 2014-03-19 | 南开大学 | 1,7,8-三氟-2-萘酚及其衍生物的制备方法 |
CN117247368A (zh) * | 2023-11-20 | 2023-12-19 | 上海如鲲新材料股份有限公司 | 一种反式二氟代碳酸乙烯酯类化合物的制备方法 |
CN117247368B (zh) * | 2023-11-20 | 2024-03-19 | 上海如鲲新材料股份有限公司 | 一种反式二氟代碳酸乙烯酯类化合物的制备方法 |
Also Published As
Publication number | Publication date |
---|---|
JPWO2003008364A1 (ja) | 2004-11-04 |
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