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WO2018126194A8 - Fibres chargées de sorbant pour procédés d'adsorption à haute température - Google Patents

Fibres chargées de sorbant pour procédés d'adsorption à haute température Download PDF

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Publication number
WO2018126194A8
WO2018126194A8 PCT/US2017/069055 US2017069055W WO2018126194A8 WO 2018126194 A8 WO2018126194 A8 WO 2018126194A8 US 2017069055 W US2017069055 W US 2017069055W WO 2018126194 A8 WO2018126194 A8 WO 2018126194A8
Authority
WO
WIPO (PCT)
Prior art keywords
sorbent
high temperature
polymer
adsorption processes
temperature adsorption
Prior art date
Application number
PCT/US2017/069055
Other languages
English (en)
Other versions
WO2018126194A1 (fr
Inventor
Philippe A. COIGNET
Dean W. KRATZER
Sudhir S. Kulkarni
JR. Edgar S. SANDERS
Original Assignee
L'Air Liquide Société Anonyme Pour L'Étude Et L'Exploitation Des Procedes Georges Claude
Air Liquide Advanced Technologies U.S. Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US15/396,644 external-priority patent/US10315184B2/en
Application filed by L'Air Liquide Société Anonyme Pour L'Étude Et L'Exploitation Des Procedes Georges Claude, Air Liquide Advanced Technologies U.S. Llc filed Critical L'Air Liquide Société Anonyme Pour L'Étude Et L'Exploitation Des Procedes Georges Claude
Priority to CN201780091040.3A priority Critical patent/CN110730686A/zh
Priority to EP17835780.2A priority patent/EP3612301A1/fr
Publication of WO2018126194A1 publication Critical patent/WO2018126194A1/fr
Publication of WO2018126194A8 publication Critical patent/WO2018126194A8/fr

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B01J20/08—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04 comprising aluminium oxide or hydroxide; comprising bauxite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B01J20/165—Natural alumino-silicates, e.g. zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/223—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material containing metals, e.g. organo-metallic compounds, coordination complexes
    • B01J20/226—Coordination polymers, e.g. metal-organic frameworks [MOF], zeolitic imidazolate frameworks [ZIF]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/26—Synthetic macromolecular compounds
    • B01J20/262—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon to carbon unsaturated bonds, e.g. obtained by polycondensation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/26—Synthetic macromolecular compounds
    • B01J20/265—Synthetic macromolecular compounds modified or post-treated polymers
    • B01J20/267—Cross-linked polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
    • B01J20/28011—Other properties, e.g. density, crush strength
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/28023—Fibres or filaments
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/28026—Particles within, immobilised, dispersed, entrapped in or on a matrix, e.g. a resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/2803—Sorbents comprising a binder, e.g. for forming aggregated, agglomerated or granulated products
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating

Landscapes

  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Artificial Filaments (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

L'invention concerne une fibre composite comprenant des particules de sorbant (à 50 % en poids) dans une matrice polymère qui comprend un polymère ou un mélange de polymères comprenant au moins un polymère thermoplastique, les extrudés étant produits par séparation de phase induite par la chaleur ou séparation de phase induite par diffusion à partir d'une suspension de dopant du polymère thermoplastique, d'un solvant facultatif et des particules de sorbant. Le polymère ou le mélange de polymères peut résister à une exposition à des températures de ou au-dessus de 220°C sans subir d'effets néfastes significatifs sur la capacité de sorbant des particules de sorbant. La fibre présente un allongement à la rupture d'au moins 5 %.
PCT/US2017/069055 2016-12-31 2017-12-29 Fibres chargées de sorbant pour procédés d'adsorption à haute température WO2018126194A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN201780091040.3A CN110730686A (zh) 2017-04-17 2017-12-29 用于高温吸附过程的加载吸着剂的纤维
EP17835780.2A EP3612301A1 (fr) 2017-04-17 2017-12-29 Fibres chargées de sorbant pour procédés d'adsorption à haute température

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201615396644A 2016-12-31 2016-12-31
US15/396,644 2017-04-17
US15/396,644 US10315184B2 (en) 2017-04-17 2017-04-17 Adsorbent-loaded beads for high temperature adsorption processes

Publications (2)

Publication Number Publication Date
WO2018126194A1 WO2018126194A1 (fr) 2018-07-05
WO2018126194A8 true WO2018126194A8 (fr) 2018-10-25

Family

ID=61028202

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2017/069055 WO2018126194A1 (fr) 2016-12-31 2017-12-29 Fibres chargées de sorbant pour procédés d'adsorption à haute température

Country Status (1)

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WO (1) WO2018126194A1 (fr)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111655365A (zh) 2017-12-31 2020-09-11 乔治洛德方法研究和开发液化空气有限公司 用于制造固体吸附剂纤维的方法
US11439978B2 (en) 2017-12-31 2022-09-13 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Method for manufacturing a solid adsorbent fiber
KR102275948B1 (ko) 2019-06-19 2021-07-13 한국과학기술원 이산화탄소 포집을 위한 구조화된 금속-유기 골격체 파이버 흡착제 및 이의 제조방법
CN113373695B (zh) * 2021-06-09 2022-06-28 中国科学院兰州化学物理研究所 一种MOFs改性PBO纤维、PBO纤维增强酚醛树脂基复合材料及其制备方法和应用
US20240269603A1 (en) * 2023-02-08 2024-08-15 Decarbontek LLC Reinforced Adsorbent Fibers and Applications

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5401706A (en) 1993-01-06 1995-03-28 Semco Incorporated Desiccant-coated substrate and method of manufacture
US6451723B1 (en) 2000-07-07 2002-09-17 Honeywell International Inc. Polymer-bound nitrogen adsorbent and method of making and using it
US6500233B1 (en) * 2000-10-26 2002-12-31 Chevron U.S.A. Inc. Purification of p-xylene using composite mixed matrix membranes
US7592284B2 (en) 2006-03-13 2009-09-22 Honeywell International Inc. Preparation of ion exchanged polymer bound nitrogen adsorbent
KR101516448B1 (ko) * 2007-06-01 2015-05-07 유오피 엘엘씨 중합체 작용기화 분자체와 중합체의 uv 가교결합된 혼합 매트릭스 멤브레인
US8133308B2 (en) 2007-06-27 2012-03-13 Georgia Tech Research Corporation Sorbent fiber compositions and methods of temperature swing adsorption
SG192607A1 (en) * 2011-02-14 2013-09-30 Univ Singapore Preparation of zeolitic imidazolate frameworks (zifs) - polybenzimidazole mixed-matrix composite and application for gas and vapor separation
KR20170005901A (ko) * 2013-12-16 2017-01-16 사빅 글로벌 테크놀러지스 비.브이. 처리된 혼합 매트릭스 중합 멤브레인들

Also Published As

Publication number Publication date
WO2018126194A1 (fr) 2018-07-05

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