KR20170064463A - 실리콘 게르마늄 주석 필름들을 형성하는 방법들 및 필름들을 포함하는 구조체들 및 디바이스들 - Google Patents
실리콘 게르마늄 주석 필름들을 형성하는 방법들 및 필름들을 포함하는 구조체들 및 디바이스들 Download PDFInfo
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- 238000000034 method Methods 0.000 title claims abstract description 77
- KAJBHOLJPAFYGK-UHFFFAOYSA-N [Sn].[Ge].[Si] Chemical compound [Sn].[Ge].[Si] KAJBHOLJPAFYGK-UHFFFAOYSA-N 0.000 title abstract description 8
- 229910052732 germanium Inorganic materials 0.000 claims abstract description 49
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims abstract description 49
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims abstract description 36
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 27
- 239000010703 silicon Substances 0.000 claims abstract description 23
- 239000002243 precursor Substances 0.000 claims description 65
- 239000000758 substrate Substances 0.000 claims description 65
- 238000006243 chemical reaction Methods 0.000 claims description 45
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 26
- 229910000077 silane Inorganic materials 0.000 claims description 26
- 229910000078 germane Inorganic materials 0.000 claims description 16
- 238000002425 crystallisation Methods 0.000 claims description 7
- 230000008025 crystallization Effects 0.000 claims description 7
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 229910001887 tin oxide Inorganic materials 0.000 claims description 2
- 230000008878 coupling Effects 0.000 claims 1
- 238000010168 coupling process Methods 0.000 claims 1
- 238000005859 coupling reaction Methods 0.000 claims 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical class O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims 1
- 229910052718 tin Inorganic materials 0.000 abstract description 30
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract description 18
- 238000004519 manufacturing process Methods 0.000 abstract description 6
- 238000005229 chemical vapour deposition Methods 0.000 abstract description 5
- 239000002019 doping agent Substances 0.000 description 20
- 229910005898 GeSn Inorganic materials 0.000 description 14
- 239000007789 gas Substances 0.000 description 13
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 7
- 229910052799 carbon Inorganic materials 0.000 description 7
- 239000012159 carrier gas Substances 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 7
- 230000005693 optoelectronics Effects 0.000 description 6
- 239000004065 semiconductor Substances 0.000 description 6
- 150000004756 silanes Chemical class 0.000 description 6
- 239000000203 mixture Substances 0.000 description 5
- 238000010926 purge Methods 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 4
- 238000011144 upstream manufacturing Methods 0.000 description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 229910045601 alloy Inorganic materials 0.000 description 3
- 239000000956 alloy Substances 0.000 description 3
- 239000007833 carbon precursor Substances 0.000 description 3
- PZPGRFITIJYNEJ-UHFFFAOYSA-N disilane Chemical compound [SiH3][SiH3] PZPGRFITIJYNEJ-UHFFFAOYSA-N 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- 238000001228 spectrum Methods 0.000 description 3
- VEDJZFSRVVQBIL-UHFFFAOYSA-N trisilane Chemical compound [SiH3][SiH2][SiH3] VEDJZFSRVVQBIL-UHFFFAOYSA-N 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
- 238000001237 Raman spectrum Methods 0.000 description 2
- 229910052581 Si3N4 Inorganic materials 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 2
- 229910052785 arsenic Inorganic materials 0.000 description 2
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 2
- 229910052796 boron Inorganic materials 0.000 description 2
- 239000013590 bulk material Substances 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 229910052805 deuterium Inorganic materials 0.000 description 2
- IWTIUUVUEKAHRM-UHFFFAOYSA-N germanium tin Chemical compound [Ge].[Sn] IWTIUUVUEKAHRM-UHFFFAOYSA-N 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- QCAWEPFNJXQPAN-UHFFFAOYSA-N methoxyfenozide Chemical compound COC1=CC=CC(C(=O)NN(C(=O)C=2C=C(C)C=C(C)C=2)C(C)(C)C)=C1C QCAWEPFNJXQPAN-UHFFFAOYSA-N 0.000 description 2
- 230000037230 mobility Effects 0.000 description 2
- 238000001451 molecular beam epitaxy Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 2
- 229910052814 silicon oxide Inorganic materials 0.000 description 2
- 239000012686 silicon precursor Substances 0.000 description 2
- 229910002066 substitutional alloy Inorganic materials 0.000 description 2
- 235000012431 wafers Nutrition 0.000 description 2
- YZCKVEUIGOORGS-OUBTZVSYSA-N Deuterium Chemical compound [2H] YZCKVEUIGOORGS-OUBTZVSYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910008310 Si—Ge Inorganic materials 0.000 description 1
- -1 Sn (CH 3 ) 4- n X n Chemical class 0.000 description 1
- MOFQWXUCFOZALF-UHFFFAOYSA-N [GeH3][GeH3] Chemical compound [GeH3][GeH3] MOFQWXUCFOZALF-UHFFFAOYSA-N 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 238000005234 chemical deposition Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000005137 deposition process Methods 0.000 description 1
- VXGHASBVNMHGDI-UHFFFAOYSA-N digermane Chemical compound [Ge][Ge] VXGHASBVNMHGDI-UHFFFAOYSA-N 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- VGRFVJMYCCLWPQ-UHFFFAOYSA-N germanium Chemical compound [Ge].[Ge] VGRFVJMYCCLWPQ-UHFFFAOYSA-N 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 125000001072 heteroaryl group Chemical group 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 229910021421 monocrystalline silicon Inorganic materials 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- 238000001020 plasma etching Methods 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000005001 rutherford backscattering spectroscopy Methods 0.000 description 1
- KXCAEQNNTZANTK-UHFFFAOYSA-N stannane Chemical class [SnH4] KXCAEQNNTZANTK-UHFFFAOYSA-N 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- QHGNHLZPVBIIPX-UHFFFAOYSA-N tin(ii) oxide Chemical class [Sn]=O QHGNHLZPVBIIPX-UHFFFAOYSA-N 0.000 description 1
- 230000007723 transport mechanism Effects 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
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Abstract
Description
도 1 은 본 개시물의 예시적인 실시형태들에 따른 하나 이상의 SixGe1-xSny 필름들을 형성하는 시스템을 예시한다.
도 2 는 본 개시물의 추가의 예시적인 실시형태들에 따른 하나 이상의 SixGe1-xSny 필름들을 형성하는 방법을 예시한다.
도 3 은 본 개시물의 예시적인 실시형태들에 따라 형성된 고정된 SiH4, GeH4, 및 SnCl4 플로우들로 성장되는 여러 조성물들의 SixGe1-xSny 층들을 보여주는 XRD 플롯을 예시한다.
도 4 는 본 개시물의 예시적인 실시형태들에 따라 형성된 5 % Sn 및 8 % Si 를 갖는, Ge 버퍼 층 상의 예시적인 SixGe1-xSny 층을 보여주는 RBS 플롯을 예시한다.
도 5 는 본 개시물의 예시적인 실시형태들에 따라 형성된 여러 SixGe1-xSny 필름들의 라만 스펙트럼을 예시한다.
도 6 내지 도 13 은 본 개시물의 또 다른 추가적 예시적인 실시형태들에 따른 예시적 구조체들을 예시한다.
도면들에서의 엘리먼트들은 단순화 및 명확화를 위하여 예시된 것으로서 반드시 일정 스케일로 도시된 것은 아님을 주지해야 한다. 예를 들어, 도면들에서 엘리먼트들의 치수들은 본 개시물의 예시된 실시형태들의 이해를 개선하도록 돕기 위하여 다른 엘리먼트들에 비해 과장될 수도 있다.
Claims (20)
- 기판 상에 SixGe1-xSny 층을 형성하는 방법으로서,
반응 공간을 갖는 반응기를 제공하는 단계;
상기 반응 공간 내에 기판을 제공하는 단계;
상기 반응 공간에 커플링된 실란을 제공하는 단계;
상기 반응 공간에 커플링된 게르마늄 전구체를 제공하는 단계;
상기 반응 공간에 커플링된 주석 전구체 소스를 제공하는 단계; 및
상기 기판의 표면에 SixGe1-xSny 의 층을 에피택셜하게 형성하는 단계를 포함하는, 기판 상에 SixGe1-xSny 층을 형성하는 방법. - 제 1 항에 있어서,
상기 게르마늄 전구체는 게르마늄 게르만을 포함하는, 기판 상에 SixGe1-xSny 층을 형성하는 방법. - 제 1 항에 있어서,
상기 기판의 표면에 SixGe1-xSny 의 층을 에피택셜하게 형성하는 단계 동안에, 상기 반응 공간의 동작 압력은 약 500 Torr 와 약 760 Torr 사이인, 기판 상에 SixGe1-xSny 층을 형성하는 방법. - 제 1 항에 있어서,
상기 SixGe1-xSny 의 층은 0 초과 내지 약 15 at% 의 주석을 포함하는, 기판 상에 SixGe1-xSny 층을 형성하는 방법. - 제 1 항에 있어서,
상기 SixGe1-xSny 의 층은 0 초과 내지 약 30 at% 의 실리콘을 포함하는, 기판 상에 SixGe1-xSny 층을 형성하는 방법. - 제 1 항에 있어서,
상기 SixGe1-xSny 의 층은 약 55 at% 내지 약 65 at% 의 게르마늄을 포함하는, 기판 상에 SixGe1-xSny 층을 형성하는 방법. - 제 1 항에 있어서,
상기 기판의 표면에 SixGe1-xSny 의 층을 에피택셜하게 형성하는 단계 동안에, 상기 반응 공간에 제공된 상기 게르마늄 전구체에 대한 상기 실란의 비는 약 2 내지 약 15 인, 기판 상에 SixGe1-xSny 층을 형성하는 방법. - 제 1 항에 있어서,
상기 기판의 표면에 SixGe1-xSny 의 층을 에피택셜하게 형성하는 단계 동안에, 상기 반응 공간에 제공된 상기 게르마늄 전구체에 대한 상기 실란의 비는 약 3 내지 약 12 인, 기판 상에 SixGe1-xSny 층을 형성하는 방법. - 제 1 항에 있어서,
상기 기판의 표면에 SixGe1-xSny 의 층을 에피택셜하게 형성하는 단계 동안에, 상기 반응 공간 내의 동작 온도는 약 275 ℃ 내지 약 475 ℃ 인, 기판 상에 SixGe1-xSny 층을 형성하는 방법. - 제 1 항에 있어서,
상기 주석 전구체 소스를 제공하는 단계는, SnCl4, SnD4, 및 메틸 및/또는 할로겐화물 치환된 주석산화물의 그룹 중 하나 이상으로부터 선택되는 주석 소스를 제공하는 단계를 포함하는, 기판 상에 SixGe1-xSny 층을 형성하는 방법. - 제 1 항에 있어서,
상기 기판의 표면에 SixGe1-xSny 의 층을 에피택셜하게 형성하는 단계는, 약 2 at% 내지 약 15 at% 의 주석을 포함하는 결정화 층을 성장시키는 단계를 포함하는, 기판 상에 SixGe1-xSny 층을 형성하는 방법. - 제 1 항에 있어서,
상기 기판의 표면에 SixGe1-xSny 의 층을 에피택셜하게 형성하는 단계는, 1 at% 내지 약 30 at% 의 실리콘을 포함하는 결정화 층을 성장시키는 단계를 포함하는, 기판 상에 SixGe1-xSny 층을 형성하는 방법. - SixGe1-xSny 층을 포함하는 구조체를 형성하는 방법으로서,
반응 공간을 포함하는 크로스-플로우 반응기를 제공하는 단계;
상기 반응 공간 내에 기판을 제공하는 단계; 및
실란 및 게르만을 이용하여 상기 기판의 표면에 SixGe1-xSny 을 포함하는 결정화 층을 형성하는 단계를 포함하는, SixGe1-xSny 층을 포함하는 구조체를 형성하는 방법. - 제 13 항에 있어서,
상기 기판은 실리콘 위에 놓이는 게르마늄을 포함한 층을 포함하는, SixGe1-xSny 층을 포함하는 구조체를 형성하는 방법. - 제 13 항에 있어서,
상기 SixGe1-xSny 을 포함한 층은 0 at% 초과의 주석 내지 약 15 at% 의 주석을 포함하는, SixGe1-xSny 층을 포함하는 구조체를 형성하는 방법. - 제 13 항에 있어서,
상기 SixGe1-xSny 을 포함한 층은 0 at% 초과의 실리콘 내지 약 30 at% 의 실리콘을 포함하는, SixGe1-xSny 층을 포함하는 구조체를 형성하는 방법. - 제 13 항에 있어서,
상기 SixGe1-xSny 을 포함한 층은 약 55 at% 의 게르마늄 내지 약 65 at% 의 게르마늄을 포함하는, SixGe1-xSny 층을 포함하는 구조체를 형성하는 방법. - 제 13 항에 있어서,
상기 기판 위에 놓이는 절연층을 형성하는 단계;
상기 절연층 내에 비아를 형성하는 단계; 및
상기 비아 내에 SixGe1-xSny 을 포함한 층을 선택적으로 형성하는 단계를 더 포함하는, SixGe1-xSny 층을 포함하는 구조체를 형성하는 방법. - 제 13 항에 기재된 방법에 따라 형성된 SixGe1-xSny 의 결정화 층을 포함하는, 구조체.
- 제 19 항에 있어서,
상기 구조체는 상기 SixGe1-xSny 의 결정화 층 위에 놓이는 게르마늄을 포함한 층을 포함하는, 구조체.
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| US9905420B2 (en) | 2018-02-27 |
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