WO1993014503A1 - Procede de production d'energie fonde sur l'affaissement gravitationnel - Google Patents
Procede de production d'energie fonde sur l'affaissement gravitationnel Download PDFInfo
- Publication number
- WO1993014503A1 WO1993014503A1 PCT/JP1993/000019 JP9300019W WO9314503A1 WO 1993014503 A1 WO1993014503 A1 WO 1993014503A1 JP 9300019 W JP9300019 W JP 9300019W WO 9314503 A1 WO9314503 A1 WO 9314503A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- cathode
- hydrogen
- deuterium
- solid
- electrolysis
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 45
- XLYOFNOQVPJJNP-ZSJDYOACSA-N Heavy water Chemical compound [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 claims abstract description 86
- 239000007787 solid Substances 0.000 claims abstract description 59
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 54
- 239000001257 hydrogen Substances 0.000 claims abstract description 53
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 50
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 41
- 239000003115 supporting electrolyte Substances 0.000 claims abstract description 19
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 claims abstract description 12
- 230000000694 effects Effects 0.000 claims abstract description 9
- 238000005868 electrolysis reaction Methods 0.000 claims description 65
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 50
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 48
- YZCKVEUIGOORGS-OUBTZVSYSA-N Deuterium Chemical compound [2H] YZCKVEUIGOORGS-OUBTZVSYSA-N 0.000 claims description 46
- 229910052805 deuterium Inorganic materials 0.000 claims description 41
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 30
- 229910052759 nickel Inorganic materials 0.000 claims description 25
- 229910052763 palladium Inorganic materials 0.000 claims description 21
- 230000003746 surface roughness Effects 0.000 claims description 19
- 229910052793 cadmium Inorganic materials 0.000 claims description 11
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 11
- 239000007788 liquid Substances 0.000 claims description 10
- 229910052709 silver Inorganic materials 0.000 claims description 10
- 229910052697 platinum Inorganic materials 0.000 claims description 9
- 230000002285 radioactive effect Effects 0.000 claims description 9
- SWELZOZIOHGSPA-UHFFFAOYSA-N palladium silver Chemical compound [Pd].[Ag] SWELZOZIOHGSPA-UHFFFAOYSA-N 0.000 claims description 8
- 239000004332 silver Substances 0.000 claims description 8
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- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 6
- 229910052705 radium Inorganic materials 0.000 claims description 6
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- AIYUHDOJVYHVIT-UHFFFAOYSA-M caesium chloride Chemical compound [Cl-].[Cs+] AIYUHDOJVYHVIT-UHFFFAOYSA-M 0.000 claims description 4
- HUCVOHYBFXVBRW-UHFFFAOYSA-M caesium hydroxide Chemical compound [OH-].[Cs+] HUCVOHYBFXVBRW-UHFFFAOYSA-M 0.000 claims description 4
- 239000011133 lead Substances 0.000 claims description 4
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- 239000011780 sodium chloride Substances 0.000 claims description 3
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- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 2
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 2
- 229910052737 gold Inorganic materials 0.000 claims description 2
- 239000010931 gold Substances 0.000 claims description 2
- 229910000856 hastalloy Inorganic materials 0.000 claims description 2
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims description 2
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims description 2
- 229910052707 ruthenium Inorganic materials 0.000 claims description 2
- FGDZQCVHDSGLHJ-UHFFFAOYSA-M rubidium chloride Chemical compound [Cl-].[Rb+] FGDZQCVHDSGLHJ-UHFFFAOYSA-M 0.000 claims 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract description 12
- UFHFLCQGNIYNRP-VVKOMZTBSA-N Dideuterium Chemical compound [2H][2H] UFHFLCQGNIYNRP-VVKOMZTBSA-N 0.000 abstract 1
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- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
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- WMFOQBRAJBCJND-DYCDLGHISA-M 12159-20-5 Chemical compound [Li+].[2H][O-] WMFOQBRAJBCJND-DYCDLGHISA-M 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
- -1 KOD Chemical compound 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
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- 241000408495 Iton Species 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
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- NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical compound [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 description 1
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- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
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- JBJWASZNUJCEKT-UHFFFAOYSA-M sodium;hydroxide;hydrate Chemical compound O.[OH-].[Na+] JBJWASZNUJCEKT-UHFFFAOYSA-M 0.000 description 1
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Classifications
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21B—FUSION REACTORS
- G21B3/00—Low temperature nuclear fusion reactors, e.g. alleged cold fusion reactors
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E30/00—Energy generation of nuclear origin
- Y02E30/10—Nuclear fusion reactors
Definitions
- the present invention generates neutron nuclei by conducting electrolysis of water or heavy water using a cathode made of a solid element, and surrounding the solid element with hydrogen and Z or deuterium in an ultrahigh pressure state. And the method of generating energy by causing gravitational collapse.
- the method of the present invention can also be carried out as a method for treating radioactive waste by using a radioactive element derived from radioactive waste as the solid element.
- the neutron nucleus in which orbital electrons and protons have disappeared from the atom, undergoes gravitational collapse, that is, the neutron nuclei themselves self-shrink due to the gravitational force between the neutrons that make up the nucleus, shrinking to a singular point It has been reported that a neutron nucleus itself can explode and release energy on an astrophysical scale when it strikes, and the energy generated by the gravitational collapse of this neutron nucleus is about 130 OMeV / neutron It is said to be. However, it has not been reported that such gravitational collapse of neutron nuclei could occur on an industrial scale under artificial control.
- the gravitational collapse of neutron nuclei can release an extremely large amount of energy, so if the gravitational collapse of neutron nuclei can be generated under mild conditions by some means, it can be a powerful energy supply method. It is expected.
- neutron nuclei are sought from ordinary elements to cause gravitational collapse of the neutron nuclei, it is possible to annihilate the raw material elements. It is possible to plan.
- an object of the present invention is to provide a method for generating energy using the gravitational collapse of neutron nuclei capable of rapidly generating energy, and a method capable of treating radioactive substances. .
- the present invention performs electrolysis of water and / or heavy water containing a supporting electrolyte using a cathode composed of one or more conductive solid elements
- the self-compression effect of hydrogen and z or deuterium on the surface and z or inside of the pole forms hydrogen and / or deuterium in ultrahigh pressure to surround the solid element of the cathode, Gravitational decay of single and / or multiple neutron nuclei generated from Z or deuterium itself and / or gravitational decay of single and / or multiple neutron nuclei generated by capturing orbital electrons of solid element nuclei
- This is a method for generating energy, which is characterized by generating energy by generating energy.
- a water containing a supporting electrolyte is formed by using a cathode composed of one or more conductive solid elements hardly occluding hydrogen and having a surface roughness of R a ⁇ 5 m. And electrolysis of Z or heavy water.
- electrolysis of water and Z or heavy water containing a supporting electrolyte is performed using a solid element containing a radioactive element derived from radioactive waste as a cathode.
- FIG. 1 is a diagram showing an example of an apparatus for performing the method of the present invention.
- FIG. 2 is a photograph showing the gravitational collapse of quadruple neutrons observed on a nuclear dry plate in Example 1.
- FIG. 3 is a diagram illustrating the photograph of FIG.
- FIG. 4 is a photograph showing the gravity decay of the itonized quadruple neutrons observed on the nucleus plate in Example 1.
- FIG. 5 is a diagram illustrating the photograph of FIG.
- FIG. 6 is a photograph showing bursts of pits observed on a nucleus plate in Example 1.
- FIG. 7 is a diagram illustrating the photograph of FIG.
- FIG. 8 is a photograph showing the simultaneous gravitational collapse of three quadruple neutrons and the generation of a tiny black hole observed on a nuclear plate in Example 1.
- FIG. 9 is a diagram illustrating the photograph of FIG.
- FIG. 10 is a photograph showing a star-like track of fission fragments due to fission observed on a nuclear dry plate in Example 1.
- FIG. 11 is a diagram illustrating the photograph of FIG. 10.
- FIG. 12 is a photograph showing evaporation of a minimal black hole observed on a nucleus plate in Example 5.
- FIG. 13 is a diagram illustrating the photograph of FIG.
- FIG. 14 is a photograph showing the emission of a very small white hole (cone-shaped white hole) observed on the nucleus plate in Example 5.
- FIG. 15 is a diagram illustrating the photograph of FIG.
- FIG. 16 is a photograph showing emission of extremely small white holes (white holes due to evaporation of black holes) observed on the nucleus plate in Example 5.
- FIG. 17 is a diagram illustrating the photograph of FIG.
- Black hole A minimal compression state of a substance due to gravity.
- White hole A mathematically symmetric solution of a black hole, a hole that releases a compact.
- Wormhole A tiny hole that is compressed by a black hole and becomes extremely small, and passes through a black hole and a white hole.
- the ultrahigh pressure state in the present invention refers to a state in which a pressure of at least several hundred atmospheres is locally applied to the peripheral portion of the element.
- the gravitational collapse referred to in the present invention is, as described above, a reaction in which neutrons constituting nuclei self-shrink due to gravity between neutrons and approach each other, contract to a singular point, and neutron nuclei explode to release energy.
- the gravitational collapse of neutron nuclei occurs because the generated neutron nuclei are surrounded by diton particles, and are generated by the diton particle compression effect.
- the reaction in the method of the present invention includes the steps of generating neutron nuclei containing single neutrons and multiple neutrons from hydrogen, deuterium and / or solid elements, and the single and / or generated nuclei. Includes the stage where multiple neutron nuclei cause gravitational collapse.
- neutron nuclei from hydrogen and deuterium atoms is considered to occur, for example, in the following manner.
- H is a hydrogen atom
- D is a deuterium atom
- e is an electron
- i is a single iton
- i 2 is a double iton
- i 3 is a triple pit
- p is a proton
- 1 n is a single neutron
- 2 n is a double neutron
- 4 n is a quadruple neutron
- d is a deuteron
- 4 H is a deuterium.
- the atomic number Z, nucleus of the element X of the mass number A, the A n represents a multiple neutron atomic nuclei. Or represents a singleton.
- the element used as a cathode in the present invention is applicable as long as it is a solid element.
- a solid element For example, Ag, Al, As, Au, Ba, Be, Bi, C, Cd, Ce, Co, Cr ⁇ Cu, Fe, Ga, Ge, Hf, Hg, In, Ir, La, Mn, Mo, Nb, Ni, 0s, P, Pa, Pb, Pd, Pt, Ra, Re, Rh, Rn, Ru, S, Sb, Sc, Se, Si, Sn, Sr, Ta, Te, Th, Ti, U, V, W, Y, Zn, Zr and the like can be mentioned, and these can be used alone or in the form of an alloy or a mixture.
- hydrogen, Z or deuterium is electrolyzed using the solid element as a cathode to surround the solid element with hydrogen and Z or deuterium molecules in an ultra-high pressure state. Must have conductivity.
- the solid element used in the present invention can be formed into an arbitrary shape and used as a cathode, and can be used in the form of a column, a prism, a plate, a fiber sheet, or the like.
- palladium or a palladium alloy can be mentioned as a preferable material that can be used as a solid element of the cathode.
- the solid element constituting the cathode may be composed only of palladium, but when the method of the present invention is carried out by electrolysis, the mechanical strength of the solid element formed on the cathode during electrolysis is reduced.
- the preferred metal that forms an alloy with palladium is silver.
- the content of silver or other solid elements in the palladium alloy is preferably 25% by weight or less. Palladium and silver or other solid elements It is preferable to use palladium-silver or other solid alloy having a fifty ratio of 75 / 25-99Z1.
- palladium or palladium alloy used as a solid-state element in this Takaaki must be heat-treated in advance at a temperature of 800 or higher in general (however, the melting point of the solid element or lower). Is preferred.
- the purpose of this heat treatment is to desorb components in the air such as nitrogen molecules adsorbed on or inside the palladium or palladium alloy.
- hydrogen and Z or deuterium are easily accessible to solid elements, generation of single and Z or multiple neutron nuclei from hydrogen and deuterium, and removal of solid elements.
- the capture of orbital electrons promotes the generation of multiple neutron nuclei and the gravitational collapse of these single and Z or multiple neutron nuclei. Insufficient desorption of the components in it will prevent hydrogen or deuterium atoms from approaching the palladium atom, making it difficult for the desired reaction to occur.
- This heat treatment is achieved by treating the solid elements in a vacuum furnace at a temperature of 800 ° C. or more and a vacuum of 10 ′′ 4 Torr or more before electrolysis. Longer time at high temperature has a greater effect, but as described above, it must be performed at a temperature lower than the melting point of the solid state.
- hydrogen or deuterium replacement is preferably performed in a hydrogen or deuterium atmosphere. Can be filled with hydrogen or deuterium at an appropriate pressure.
- the solid element used in the method of the present invention is converted into a nuclear state and then splits into multiple neutrons and other particles, and the multiple neutrons are converted into energy by gravity decay. Therefore, if the radioactivity derived from radioactive waste is used as a solid element in the method of the present invention, the radioactive element can be extinguished, and the radioactive waste treatment method Is extremely useful. Particularly effective in the elimination processing of various radioactive elements from nuclear power plants, 238 U these nuclear fuel radioactive elemental generated by capturing neutrons, 237 Np, 23 S Pu, 241 Pu, 2 42 Am and, 1 37 Cs produced by nuclear fission in addition to this, such as, 133 Cs, there is s ° Sr or the like.
- the reprocessing of these radioactive wastes is carried out by treating spent nuclear fuel with nitric acid solution by nitric acid treatment. Then, the mixture is extracted with an organic solvent (for example, a kerosene solution containing tributyl phosphate), separated into an aqueous phase and an organic solvent phase, and further appropriately subjected to post-treatments such as ion exchange and neutralization treatment. It has been sealed in drums and stored strictly for a long time. If the present invention is applied, it is technically possible to extinguish by gravitational collapse while generating energy without performing the above-mentioned treatment, which is of great industrial significance.
- an organic solvent for example, a kerosene solution containing tributyl phosphate
- the rougher the surface of the cathode used in the present invention the lower the hydrogen overvoltage, and the longer the time required for the gravitational collapse of the neutron nucleus to occur after the start of electrolysis.
- it is smooth.
- the average roughness Ra expressed in accordance with JIS B0106
- the roughness is more preferably Ra ⁇ 1 Rm, and even more preferably Ra ⁇ 0. It is desirable that the entire surface of the cathode immersed in water, Z or heavy water during electrolysis has the above roughness.
- cathodes having a greater surface roughness than those described above can also be used in the present invention.
- the element which can be used as the cathode having the above-mentioned surface roughness in the present invention is a solid in water and / or heavy water electrolysis, is insoluble in water and Z or heavy water, has conductivity, and has hydrogen. Any material that is hardly permeated and hardly occludes hydrogen inside, that is, hardly occludes hydrogen, can be used as long as the surface can be finished to the above surface roughness and the hydrogen overvoltage can be increased. In particular, since it is necessary to finish the surface to the above-mentioned surface roughness, it is preferable to select from metal and carbon.
- cathode materials examples include iridium, ruthenium, silver, copper, nickel, cadmium, iron, indium, zinc, tin, aluminum, lead, gold, platinum, stainless steel (sus-316, SUS-316L, sus-310, sus-304, etc.), Hastelloy, silver nickel nickel and the like.
- Particularly preferred cathode materials are pure nigels and force domes.
- the cathode material Prior to use in the method of the invention, can be electropolished by electrolyzing water with a supporting electrolyte used as an anode. Preferably, after mechanical polishing, finish by electrolytic polishing.
- the cathode having the above-mentioned surface roughness used in the present invention may be used in any shape, but is preferably in the form of a plate, a woven sheet, a wire or a foil.
- the desired effect can be obtained by finishing the main plane surface to the specified surface roughness.
- the surface of the sickle constituting the sheet has the above surface roughness.
- the surface roughness of such fibers can be obtained by electropolishing.
- a non-woven sheet made of sintered metal fibers of nickel, stainless steel, titanium or the like having a diameter of several m to several tens of m / m is used.
- the thickness is about 0.1 to 10 thighs and the basis weight is about 100 to 800 g / m 2 .
- a nickel-woven fabric sheet suitable for use as a cathode for water electrolysis include, for example, Naslon CNP nickel sheet manufactured by Nippon Seisen Co., Ltd.
- the anode material is not particularly limited, but it is preferable to use platinum or a platinum-plated titanium anode.
- the shape of the anode is not particularly limited, but is preferably provided so as to surround the cathode. Therefore, for example, when a plate-shaped or fiber-sheet-shaped cathode is used, two anodes, a platinum wire provided spirally around the cathode or the fiber-sheet-shaped cathode at regular intervals, or ⁇ It is preferable to use an anode composed of two platinum plates, a platinum mesh, a platinum-plated titanium plate or a platinum-plated titanium mesh provided in parallel to the surface.
- water and Z or heavy water are electrolyzed, that is, water, heavy water or a mixture thereof is electrolyzed.
- water contains about 0.17% by weight of heavy water. Therefore, in practice, a mixture of water and heavy water containing about 0.17 weight of heavy water is the source of electrolysis.
- the content of heavy water is not particularly limited.However, from the viewpoint of generation of multiple neutron nuclei, the content of heavy water is preferably high, and heavy water with a purity of 99.5% or more should be used. Is preferred. On the other hand, it is preferable that the content of heavy water is not so high from the viewpoint of safety, easiness or cost of operation, and the condition can be determined by considering each condition.
- a supporting electrolyte is added to the water and Z or heavy water to be electrolyzed to ensure electrical conductivity.
- the type of the supporting electrolyte is not particularly limited as long as the purpose can be achieved.
- the supporting electrolyte is a salt or hydroxide of an alkali metal, and more preferably, NaC1, KC1, LiCl, RbCK. CsCl, NaOH, KOH, LiOH,
- Na 2 C0 3, K 2 C0 3, Li 2 C0 3, are selected from Rb 2 C0 3 and Cs 2 C0 3.
- LiOD, NaOD, KOD, RbOD and CsOD are added only when electrolyzing heavy water, but others can be added to both water and heavy water.
- a small amount (several ppm to several hundred ppm) of silica, an aluminum compound, iron oxide, or the like can be added together with these supporting electrolytes.
- the cell voltage and current density used in the electrolysis are not particularly limited as long as the reaction leading to the gravitational collapse of neutron nuclei as described above can be caused. It is desirable to make the mE and cathode current density sufficiently high. In particular, increasing the cathode current density increases the hydrogen overvoltage, generates hydrogen and Z or deuterium in an ultra-high pressure state on the surface and / or inside of the cathode to generate hydrogen and Z or deuterium, and even solids A self-compressive effect is created for the orbital atoms in the shape of a circle, making it easier for gravity collapse to occur.
- the cell voltage is preferably 3 volts or more, more preferably 10 volts or more, and the current density is preferably 1 AZdm 2 or more, more preferably
- the electrolysis is preferably performed at 5 AZdm 2 or more, particularly preferably at 10 AZdm 2 or more.
- the hydrogen group and Z or the deuterium group mainly cause nuclear fusion reactions and make an effort for energy, but they are not efficient. It is not preferable because it generates radioactive materials.
- the current value is changed every tens of minutes or every several hours, or continuously in a pulse form of, for example, several tens to several hundreds of hertz.
- the desired reaction can be triggered, that is, the generation of single and Z or multiple neutron nuclei and their gravitational collapse can be promoted.
- the membrane material include a fluorine-based cation exchange membrane (a polyperfluorosulfonic acid membrane manufactured by DuPont USA, such as Naphion 117, 415, 417, 422, 550), and the like.
- Porous fluororesin membrane Naflon diaphragm manufactured by Nichias Co., Ltd., Goatex diaphragm manufactured by Japan Pagotex Co., Ltd., porous Teflon membrane manufactured by Nitto Denko Corporation, Teflon membrane containing potassium titanate powder, etc.), porous polypropylene Membrane (Polyplastics Co., Ltd.'s Jyuragard etc.), Porous ceramic film (Nippon Tokuhoku Co., Ltd.'s ⁇ -alumina film and nickel oxide film, etc.), Asbestos diaphragm (Other than just asbestos diaphragm, Teflon fiber, elastomer) It is possible to use a polymer film having a wakefulness and chemical resistance, such as a porous polyphenylene sulfide film. Hydrogen or deuterium separated by providing these membranes can be used for fuel cells, hydrogen bottles, etc., and can be used as a hybrid between water electrolysis or heavy water electrolysis
- the electrolytic cell is used as a closed system, and the gas generated by electrolysis is taken out of the system via the pressure regulating valve so that the inside of the electrolytic cell is pressurized by the pressure regulating valve.
- the electrolytic cell is preferably placed in a closed pressurized container and pressurized with nitrogen gas, and electrolysis is preferably performed inside and outside the electrolytic bath by using a pressure regulating valve to make the pressure equal.
- a gas-liquid separator is provided outside the closed pressurized vessel and in front of the pressure regulating valve, and gas discharged from the electrolytic cell is introduced into the gas-liquid separator to liquefy and separate a part of steam or heavy steam. It is also preferable to recycle to the electrolytic cell.
- There is a danger of explosion if hydrogen or deuterium and oxygen come into contact with each other in a pressurized state. Forcibly remove the generated gas by suctioning it out of the electrolytic cell system, or separate the cathode and anode from each other with a diaphragm, Deuterium and oxygen need to be separately taken out of the system.
- the method of the present invention When the method of the present invention is carried out, it is considered to occur after a certain period of time has elapsed after the start of electrolysis.
- the temperature of the cathode is raised or lowered, or a DC voltage is applied to move hydrogen or deuterium on the cathode in the system, or the cathode is installed so that the whole is submerged in the electrolyte.
- a trigger By pulling up and moving hydrogen or deuterium on the cathode over the cathode, a trigger can be given to the above-described reaction leading to gravitational collapse of neutron nuclei.
- FIG. 1 shows an example of an electrolysis apparatus for carrying out the method of the present invention.
- the apparatus shown in FIG. 1 has a plate-shaped cathode made of a solid element, and an anode made of a platinum wire provided so as to spirally surround the plate-shaped cathode at regular intervals. It is.
- 1 is a cathode made of a solid element
- 2 is a platinum wire anode
- 3 is water and Z or heavy water to which a supporting electrolyte has been added
- 4 is a thermometer
- 5 is an internal cell
- 6 is a water level
- 7 is a thermometer.
- Couple, 8 indicates glass, quartz, Teflon, methacrylic resin or Teflon-lined stainless steel electrolytic cell
- 9 indicates hydrogen or deuterium and oxygen.
- the method of the present invention is carried out by directly immersing the anode and the cathode in water, Z or heavy water, applying a voltage between the electrodes, and performing electrolysis, and is also used in a hydrogen fuel cell.
- a gas diffusion electrode in which a platinum catalyst supported on fine-particle carbon is coated on the surface of a gas-permeable carbon fiber cloth together with a binder.
- An alloy rod of palladium-silver having a composition of 9100 weight ratio of palladium-silver instead of the palladium rod of Example 1 (diameter: 5 cm, length: 5 cm, 800 ° C., 10 ′′ e Torr Water or heavy water electrolysis was carried out in the same manner as in Example 1 except that the degassing treatment was performed in a vacuum furnace for 10 hours at a temperature of 10%. The temperature rose rapidly to 250-300 ° C, and the water temperature also gradually increased to about 80 ° C.
- Example 1 double neutrons and single pits were mainly detected during light water electrolysis from nuclear dry plates, while quadruple neutrons and double pits were mainly detected during heavy water electrolysis.
- part of the palladium-silver alloy rod is released due to gravity collapse, causing local cracks and pinholes, a slight decrease in weight, and the formation of grain-shaped defects by a scanning electron microscope. It was recognized that no. The disappearance of the radium element was confirmed. The composition of the palladium silver alloy was slightly changed.
- Example 1 Using K 2 C0 3 in place of NaOH or NaOD the supporting electrolyte of Example 1, was carried out by following the procedure of electrolysis as in Example 1 except that 3 weight K 2 C0 3 water was used as the electrolyte. As a result, the temperature of the palladium rod rapidly increased 10 days after the start of electrolysis to reach 250 to 300 ° C, and the water temperature rose to about 8 (TC).
- Example 4 5 mg of cadmium powder was added to 1.177 g of palladium powder, and both were melted and placed in a mold to produce a rod 5 cm in diameter and 5 cm in length.
- a tungsten plate was irradiated with an electron beam using an electron linear accelerator with an output energy of 48 MeV to generate neutrons of about 2 MeV, which was decelerated to 0.025 MeV with water.
- Cadmium was converted to radioactive cadmium by irradiating and irradiating a radium rod with force cadmium.
- the radiated cadmium-containing palladium rod was used as a cathode, the cathode current density was 15 A / dm 2 , the cell voltage was about 10 V, and the other conditions were the same as in Example 1 except that 3% NaOH was contained. Electrolysis was performed in heavy water. 10 days after the start of electrolysis, the number of cathode rods was 20 to 300 days. Rose to C. Gamma clear distinction spectrum of cadmium results measured by the Ge detector, and about 1 of the added 1 1 5 Cd disappears, observed that happened that reaction leading to gravitational collapse of the neutron nuclear force Domiumu element Was done.
- the Nigel plate electropolished as above is used as the cathode
- the platinum wire is used as the anode
- the cathode current density is 2 AZdra 2 and the cell voltage is about 3.5 V.
- the temperature of the nickel plate was 16. C to 28 ° C.
- the current was increased to a cathode current density of 6 A / dm 2 and a cell voltage of about 7 V.
- the temperature of the Nigger plate rapidly increased from 37 ° C to 70, abnormal heat generation continued for more than 10 hours. . Following this, the liquid temperature gradually increased from 16 and reached 65 ° C.
- a nuclear emulsion plate one side of a methacrylic resin plate or an emulsion for autoradiography manufactured by Fuji Photo Film Co., Ltd., EM type MA-7B was placed on each side in close proximity to the outside of the glass electrolytic bath. Coated to a thickness of 0 m ) was placed. Double neutrons and single ditons were mainly detected in the nuclear slab, and multiple neutrons due to nickel nuclei were also detected (see Figs. 12 to 17).
- Example 5 Instead of light water, heavy water having a purity of 99.5% was used, and thereafter, electropolishing and electrolysis were performed under the same conditions as in Example 5.
- the nickel temperature at the start of electrolysis after polishing was 21 ° C, but after the start of electrolysis the nickel plate temperature gradually increased to 32 ° C after 50 minutes, and the cathode current density after 50 minutes. When the current was increased to 6 A / dm 2 and the cell voltage was about 6 V, the temperature of the nickel plate rapidly increased to 78 ° C, and abnormal heat generation continued for 10 hours or more. The temperature of the solution gradually increased from 21 ° C and reached 72.
- the force-dummy plate was electropolished in 200 ml of a 3.3% by weight aqueous K0H solution under the same conditions as in Cold Working Example 5.
- electrolysis was performed by applying a direct current so that the cathode current density was 2 AZdm 2 and the cell voltage was about 3 V using the force-dummy plate electropolished as described above as a cathode and a platinum wire as an anode.
- the temperature of the force-dummy plate gradually increased from 18 ° C, and reached 39 ° C 51 minutes after energization.
- the current was increased so that the cathode current density was 6AZdm 2 and the cell voltage was about 4.5 V
- the temperature of the force-dummy plate rapidly increased to 71 ° C, and abnormal heat generation continued for more than 10 hours.
- the liquid temperature gradually increased from 18 ° C to 67 ° C.
- Double neutrons and single neutrons were mainly detected in the nuclei plates provided in the same manner as in Example 5, and multiple neutrons caused by force nuclei were also detected.
- Example 5 the electrolysis was started by applying a direct current at a cathode current density of 2 AZdra 2 and a cell voltage of about 3 V using the nickel plate electropolished as described above as a cathode and a platinum wire as an anode.
- the temperature of the nickel plate gradually increased from 21 ° C, and reached 32 after 50 minutes.
- the current was increased so that the cathode current density was 7 AZdm 2 and the cell voltage was about 6 V
- the temperature of the Nigger plate rapidly increased to 78 ° C, and abnormal heat generation continued for more than 10 hours.
- the liquid temperature gradually increased from 21 ° C to 71 ° C. Double neutrons and single neutrons were mainly detected in the nuclei plates provided in the same manner as in Example 5, and multiple neutrons due to nil nuclei were also detected.
- a DC was applied so that a cathode current density of 1 A / dm 2 and a cell voltage of about 3 V were applied using the roll-shaped force-dominating foil electropolished as described above as a cathode and a platinum wire as an anode, and electrolysis was started.
- the temperature of the foil gradually increased from 21 ° C, and reached 28 ° C 50 minutes after energization.
- the current was further increased to a cathode current density of 3 A / dm 2 and a cell voltage of about 5 V, the temperature of the force-dummy foil rapidly increased to 78 ° C 30 minutes later, and abnormal heat generation continued at 10 o'clock.
- a cathode current density of 1 A / dm 2 and a cell voltage of about 3 V were applied using the roll-shaped force-dominating foil electropolished as described above as a cathode and a platinum wire as an anode, and electrolysis was started.
- the temperature of the foil gradually increased
- the liquid temperature gradually increased from 21 ° C to 53 ° C.
- Double neutrons and single neutrons were mainly detected in the nuclei plates provided in the same manner as in Example 5, and multiple neutrons caused by force nuclei were also detected.
- Example 5 a nickel fiber sheet electropolished as described above was used as a cathode, and a platinum wire was used as an anode, and a direct current was applied so that the cathode current density was 2 AZdm 2 and the cell voltage was about 3.5 V.
- the electrolysis was started, the temperature of the Niger tissue sheet gradually increased from 21 ° C, and reached 35 after 50 minutes of energization.
- the cathode current density was increased to lOAZdm 2 , and the cell voltage was increased to about 8 V.
- pulsed electrolysis was performed at 100 Hz, the temperature of the Nigel fiber sheet rapidly increased to 80 ° C, and abnormal heat generation for 10 hours or more Followed. As a result, the liquid temperature gradually increased from 21 ° C to 75 ° C.
- the present invention provides a very efficient energy generation method. Further, it is possible to extinguish radioactive elements by the method of the present invention.
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- Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Plasma & Fusion (AREA)
- General Engineering & Computer Science (AREA)
- High Energy & Nuclear Physics (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Abstract
Procédé de production d'énergie présentant un rendement extrêmement élevé, consistant à électrolyser de l'eau contenant un électrolyte de support et/ou de l'eau lourde en utilisant une cathode composée d'au moins un type d'élément solide conducteur; à former des hydrogènes à pression ultraélevée et/ou des hydrogènes lourds à pression ultraélevée à la surface et/ou sur le côté interne de la cathode d'un élément solide grâce à l'effet d'autocompression des hydrogènes et/ou des hydrogènes lourds et à en entourer l'élément solide de la cathode; à provoquer l'affaissement gravitationnel du noyau d'un neutron simple et/ou multiple produit par l'hydrogène et/ou l'hydrogène lourd, et/ou l'affaissement gravitationnel du noyau d'un neutron simple et/ou multiple produit lorsque l'électron orbital du noyau de l'élément solide est capturé.
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Cited By (6)
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WO1999005683A1 (fr) * | 1997-07-24 | 1999-02-04 | Blanchard Rheal | Procede d'induction de capture electronique par les protons |
WO1999019881A1 (fr) * | 1996-10-15 | 1999-04-22 | Patterson James A | Transmutation nucleaire electrolytique a basse temperature |
WO1999045544A1 (fr) * | 1998-02-18 | 1999-09-10 | Jun Toyama | Cuve de reacteur a fusion holographique pour hologramme d'oscillation accordable de matrice laser a semiconducteurs utilisant conjointement une cuve a hologramme d'oscillation accordable de matrice laser a semiconducteurs et des ondes gravitationnelles, procede d'holographie par ondes gravitationnelles et appareil afferent |
WO1998042035A3 (fr) * | 1997-03-19 | 2000-01-20 | James A Patterson | Cellule electrolytique et procede servant a desactiver une matiere radioactive |
WO2003098640A3 (fr) * | 2002-05-17 | 2004-08-19 | Oregon State | Traitement de materiaux radioactifs avec des noyaux d'isotope d'hydrogene |
US7244887B2 (en) | 2000-02-25 | 2007-07-17 | Lattice Energy Llc | Electrical cells, components and methods |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1999019881A1 (fr) * | 1996-10-15 | 1999-04-22 | Patterson James A | Transmutation nucleaire electrolytique a basse temperature |
WO1998042035A3 (fr) * | 1997-03-19 | 2000-01-20 | James A Patterson | Cellule electrolytique et procede servant a desactiver une matiere radioactive |
WO1999005683A1 (fr) * | 1997-07-24 | 1999-02-04 | Blanchard Rheal | Procede d'induction de capture electronique par les protons |
WO1999045544A1 (fr) * | 1998-02-18 | 1999-09-10 | Jun Toyama | Cuve de reacteur a fusion holographique pour hologramme d'oscillation accordable de matrice laser a semiconducteurs utilisant conjointement une cuve a hologramme d'oscillation accordable de matrice laser a semiconducteurs et des ondes gravitationnelles, procede d'holographie par ondes gravitationnelles et appareil afferent |
US7244887B2 (en) | 2000-02-25 | 2007-07-17 | Lattice Energy Llc | Electrical cells, components and methods |
WO2003098640A3 (fr) * | 2002-05-17 | 2004-08-19 | Oregon State | Traitement de materiaux radioactifs avec des noyaux d'isotope d'hydrogene |
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