WO1993016004A1 - Thermal method for cleaning waste water - Google Patents
Thermal method for cleaning waste water Download PDFInfo
- Publication number
- WO1993016004A1 WO1993016004A1 PCT/AT1993/000015 AT9300015W WO9316004A1 WO 1993016004 A1 WO1993016004 A1 WO 1993016004A1 AT 9300015 W AT9300015 W AT 9300015W WO 9316004 A1 WO9316004 A1 WO 9316004A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- heat exchanger
- heat
- evaporator coil
- superheater
- line
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 30
- 239000002351 wastewater Substances 0.000 title abstract description 5
- 238000004140 cleaning Methods 0.000 title abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 19
- 238000001704 evaporation Methods 0.000 claims description 6
- 230000008020 evaporation Effects 0.000 claims description 5
- 238000000746 purification Methods 0.000 claims description 4
- 239000012535 impurity Substances 0.000 claims description 3
- 230000005494 condensation Effects 0.000 abstract 1
- 238000009833 condensation Methods 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 239000008235 industrial water Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000032258 transport Effects 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/02—Treatment of water, waste water, or sewage by heating
- C02F1/04—Treatment of water, waste water, or sewage by heating by distillation or evaporation
- C02F1/048—Purification of waste water by evaporation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D1/00—Evaporating
- B01D1/26—Multiple-effect evaporating
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/30—Wastewater or sewage treatment systems using renewable energies
- Y02W10/37—Wastewater or sewage treatment systems using renewable energies using solar energy
Definitions
- the invention relates to a method for thermal process water purification.
- the object of the invention is therefore to avoid these disadvantages and to provide a simple, inexpensive method which can be carried out with little energy expenditure.
- the invention solves the problem in that a large number of heat exchangers fed with process water are connected in cascade, in that the process water in each heat exchanger is evaporated via an evaporator unit, in that the steam generated in each heat exchanger for evaporating the process water in this heat exchanger
- the following heat exchanger is used so that each heat exchanger is kept at a constant temperature, the first heat exchanger being fed from an external source, and the temperature difference between the heat exchangers due to the evaporation of the process water is indicated by the heat exchangers ⁇ ordered superheater is compensated, and that cleaned condensate is removed from each evaporator unit.
- the method is characterized in that the medium which feeds the superheater is collected after it has passed through the heat exchanger and is used to feed the evaporator unit of the first heat exchanger.
- Another feature of the invention is that the medium which feeds the superheater is passed to a consumer after it has passed through the heat exchanger and that the heat removed from the last heat exchanger is used to feed the evaporator unit of the first heat exchanger.
- the invention further relates to a device for performing the method according to the invention, which is characterized in that each heat exchanger has a superheater, an evaporator coil and a feed line for the process water, that each evaporator coil at its outlet from the heat exchanger is connected to a conduit transporting line, that each heat exchanger is provided in its upper area with a line that transports the generated steam into the next heat exchanger and is connected to a further evaporator coil, and that each superheater is provided with is connected to the external heat source.
- each heat exchanger is provided with an outlet for the remote impurities.
- each superheater has a discharge line for the medium flowing through it, which is connected to a collecting line, and that the collecting line is connected to the feed line of the evaporator coil of the first heat exchanger.
- the device is characterized in that the discharge line of each superheater is coupled to a consumer and that the discharge line for the steam of the last heat exchanger is connected to the inlet of the evaporator coil of the first heat exchanger.
- FIG. 1 shows an arrangement of a plurality of heat exchangers 1, 1 ', 1'',1''', each of which is supplied with process water via a process water pipe 2.
- Each heat exchanger is in its upper area with a superheater 3, 3 ', 3'',3''' and an evaporator coil 4, 4 ', 4'',4'' and an outlet 5, 5 ', 5 '', 5 ''', by means of which the settled impurities are removed from the heat exchanger.
- the evaporator coil 4 is connected via a feed line 6 to an external heat source, not shown. For example, superheated steam runs through the evaporator coil.
- This contaminated process water is now evaporated in the heat exchanger filled with process water to just below the superheater 4.
- the steam is led in the area of the superheater via a line 7 into the evaporator coil 4 'of the next heat exchanger.
- the custom relaxed, superheated steam passing through the evaporator coil 4 is discharged as condensate via the line 8 and discharged for further use in a collecting line 9 to which all evaporator coils are connected.
- the medium cleaned in this way can be used as desired.
- the process described for the first heat exchanger is now repeated in every further heat exchanger.
- the superheater 3 Since the steam leaving the first heat exchanger naturally has a lower temperature than the medium passing through the first evaporator coil 4, the superheater 3 'is used in this heat exchanger in order to restore the temperature prevailing in the heat exchanger 1. This process is repeated in all other heat exchangers.
- the superheaters are also powered by the external heat source. All heat exchangers are kept at a constant temperature. However, only the surfaces and blowdown losses have to be covered additionally. All other heat of evaporation is passed on from one heat exchanger to the next heat exchanger. Only a small amount of heat has to be added with the superheaters.
- FIG.2 A particularly favorable embodiment of the invention is shown in Fig.2.
- the superheaters 3, 3 ', 3'',3''' fed by the external heat source have a discharge line 9, 9 ', 9'',9''', which lead to a collecting line 10 which carries the medium , which has released only a small part of its energy in the individual heat exchangers, leads back again into the feed line 6 for the first evaporator coil 4.
- the further supply of the evaporator coil directly from the external heat source can now be omitted. From this point in time, the superheater 3 also works in the heat exchanger 1, which was initially not used when the hot water was heated exclusively by the external heat source.
- the heat balance is significantly improved by this circuit, since the superheated steam has a much lower heat of vaporization.
- a large number of heat exchangers can be operated.
- the number of heat exchangers to be used depends on the boundary conditions such as e.g. B pressure and temperature dependent and is based in particular on the ratio of evaporation energy to superheating energy. 1
- FIG. 3 Another training shown in FIG. 3 is also conceivable.
- the medium emerging from the superheaters does not go into a manifold 10 as shown in the exemplary embodiment according to FIG. 2, but is fed directly to a consumer.
- the discharge line 7 '' 'for the steam generated in the last heat exchanger is connected to the evaporator coil 4 de first heat exchanger 1, i.e. h, the energy remaining in the last heat exchanger is fed to the first heat exchanger.
- the cleaned condensate is removed as in the previous examples and can be used for any purpose.
- the superheaters 3, 3 ', 3' ', 3' '' keep the heat exchangers at a constant temperature by adding little energy.
- the exemplary embodiment shown in example 2 could be used for water provision for solar hydrogen production.
- the embodiment shown in Example 3 could be used in a heating center where the medium emerging from the superheaters is fed to a boiler.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
Abstract
Description
Claims
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AU33373/93A AU670056B2 (en) | 1992-02-10 | 1993-02-08 | Thermal method for cleaning waste water |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ATA221/92 | 1992-02-10 | ||
| AT0022192A AT397078B (en) | 1992-02-10 | 1992-02-10 | METHOD AND DEVICE FOR THERMAL HOT WATER CLEANING |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO1993016004A1 true WO1993016004A1 (en) | 1993-08-19 |
Family
ID=3484753
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/AT1993/000015 WO1993016004A1 (en) | 1992-02-10 | 1993-02-08 | Thermal method for cleaning waste water |
Country Status (3)
| Country | Link |
|---|---|
| AT (1) | AT397078B (en) |
| AU (1) | AU670056B2 (en) |
| WO (1) | WO1993016004A1 (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0597594A3 (en) * | 1992-10-16 | 1995-03-15 | Chen Chan Ming | Fountain purifying water by saving energy capable of providing hot, lukewarm or ice-cold distilled water. |
| WO1995012549A1 (en) * | 1993-11-05 | 1995-05-11 | Sunds Defibrator Industries Ab | Method of purifying waste water |
| EP0757016A3 (en) * | 1995-08-04 | 1997-07-30 | Bipiemme S R L | Purification, regeneration and recycling process for industrial sewage |
| WO2010009259A3 (en) * | 2008-07-16 | 2010-04-15 | Tiax Llc | Devices and method for removing impurities from water using low grade heat |
| EP2839870A1 (en) * | 2013-08-21 | 2015-02-25 | Rafaël Van Bogaert | Distillation plant, desalinisation plant, and method of distilling water. |
| CN104548636A (en) * | 2014-12-26 | 2015-04-29 | 淄博广通化工有限责任公司 | Concentration and evaporation device for zirconium oxychloride production process |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2219650A1 (en) * | 1971-04-22 | 1972-12-14 | Saari, Risto Vaino Juhani, Luoma, Huhta Koivisto, Esko Ensio, Helsinki, (Finnland) | Distillation process and apparatus for carrying out the process |
| AT353193B (en) * | 1976-01-07 | 1979-10-25 | Hoiss Jakob | METHOD AND DEVICE FOR DISTILLING RAW WATER |
-
1992
- 1992-02-10 AT AT0022192A patent/AT397078B/en not_active IP Right Cessation
-
1993
- 1993-02-08 WO PCT/AT1993/000015 patent/WO1993016004A1/en active Application Filing
- 1993-02-08 AU AU33373/93A patent/AU670056B2/en not_active Ceased
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2219650A1 (en) * | 1971-04-22 | 1972-12-14 | Saari, Risto Vaino Juhani, Luoma, Huhta Koivisto, Esko Ensio, Helsinki, (Finnland) | Distillation process and apparatus for carrying out the process |
| AT353193B (en) * | 1976-01-07 | 1979-10-25 | Hoiss Jakob | METHOD AND DEVICE FOR DISTILLING RAW WATER |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0597594A3 (en) * | 1992-10-16 | 1995-03-15 | Chen Chan Ming | Fountain purifying water by saving energy capable of providing hot, lukewarm or ice-cold distilled water. |
| WO1995012549A1 (en) * | 1993-11-05 | 1995-05-11 | Sunds Defibrator Industries Ab | Method of purifying waste water |
| AU678081B2 (en) * | 1993-11-05 | 1997-05-15 | Sunds Defibrator Industries Ab | Method of purifying waste water |
| EP0757016A3 (en) * | 1995-08-04 | 1997-07-30 | Bipiemme S R L | Purification, regeneration and recycling process for industrial sewage |
| WO2010009259A3 (en) * | 2008-07-16 | 2010-04-15 | Tiax Llc | Devices and method for removing impurities from water using low grade heat |
| EP2839870A1 (en) * | 2013-08-21 | 2015-02-25 | Rafaël Van Bogaert | Distillation plant, desalinisation plant, and method of distilling water. |
| CN104548636A (en) * | 2014-12-26 | 2015-04-29 | 淄博广通化工有限责任公司 | Concentration and evaporation device for zirconium oxychloride production process |
| CN104548636B (en) * | 2014-12-26 | 2016-05-18 | 淄博广通化工有限责任公司 | Concentration and evaporation device in zirconium oxychloride production technology |
Also Published As
| Publication number | Publication date |
|---|---|
| ATA22192A (en) | 1993-06-15 |
| AU670056B2 (en) | 1996-07-04 |
| AU3337393A (en) | 1993-09-03 |
| AT397078B (en) | 1994-01-25 |
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