WO1996009423A1 - Agent a base organique servant au derouillage de surfaces, son procede de fabrication et son utilisation - Google Patents
Agent a base organique servant au derouillage de surfaces, son procede de fabrication et son utilisation Download PDFInfo
- Publication number
- WO1996009423A1 WO1996009423A1 PCT/EP1995/003670 EP9503670W WO9609423A1 WO 1996009423 A1 WO1996009423 A1 WO 1996009423A1 EP 9503670 W EP9503670 W EP 9503670W WO 9609423 A1 WO9609423 A1 WO 9609423A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- iron
- agent
- agents
- rust
- rust removal
- Prior art date
Links
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 title claims abstract description 34
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 85
- 229910052742 iron Inorganic materials 0.000 claims abstract description 31
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 26
- 238000000034 method Methods 0.000 claims abstract description 17
- 244000005700 microbiome Species 0.000 claims abstract description 6
- 150000002894 organic compounds Chemical class 0.000 claims abstract 3
- -1 iron ions Chemical class 0.000 claims abstract 2
- 102000008857 Ferritin Human genes 0.000 claims description 12
- 108050000784 Ferritin Proteins 0.000 claims description 12
- 238000008416 Ferritin Methods 0.000 claims description 12
- 239000000589 Siderophore Substances 0.000 claims description 10
- 238000007654 immersion Methods 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 235000015097 nutrients Nutrition 0.000 claims description 5
- 239000002738 chelating agent Substances 0.000 claims description 4
- 102000008133 Iron-Binding Proteins Human genes 0.000 claims description 3
- 108010035210 Iron-Binding Proteins Proteins 0.000 claims description 3
- 210000004027 cell Anatomy 0.000 claims description 3
- 102000004169 proteins and genes Human genes 0.000 claims description 3
- 108090000623 proteins and genes Proteins 0.000 claims description 3
- 230000001680 brushing effect Effects 0.000 claims description 2
- 239000000969 carrier Substances 0.000 claims description 2
- 210000003764 chromatophore Anatomy 0.000 claims description 2
- 239000008139 complexing agent Substances 0.000 claims description 2
- 230000000717 retained effect Effects 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- 230000000813 microbial effect Effects 0.000 claims 3
- 238000007598 dipping method Methods 0.000 claims 2
- 239000002028 Biomass Substances 0.000 claims 1
- 239000012876 carrier material Substances 0.000 claims 1
- 230000014759 maintenance of location Effects 0.000 claims 1
- 239000012528 membrane Substances 0.000 claims 1
- 238000002360 preparation method Methods 0.000 claims 1
- 238000000926 separation method Methods 0.000 claims 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 abstract description 20
- 229910052751 metal Inorganic materials 0.000 abstract description 16
- 239000002184 metal Substances 0.000 abstract description 16
- 235000013980 iron oxide Nutrition 0.000 abstract description 2
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 abstract description 2
- 150000003839 salts Chemical class 0.000 abstract description 2
- 238000010170 biological method Methods 0.000 abstract 1
- 238000011109 contamination Methods 0.000 abstract 1
- 238000012258 culturing Methods 0.000 abstract 1
- 150000007522 mineralic acids Chemical class 0.000 abstract 1
- 230000007935 neutral effect Effects 0.000 abstract 1
- 238000006386 neutralization reaction Methods 0.000 abstract 1
- 150000007524 organic acids Chemical class 0.000 abstract 1
- 238000004064 recycling Methods 0.000 abstract 1
- 230000007797 corrosion Effects 0.000 description 26
- 238000005260 corrosion Methods 0.000 description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 25
- 239000010410 layer Substances 0.000 description 13
- 230000015572 biosynthetic process Effects 0.000 description 8
- 239000000463 material Substances 0.000 description 7
- 241000191967 Staphylococcus aureus Species 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 5
- 238000003860 storage Methods 0.000 description 5
- 241000588724 Escherichia coli Species 0.000 description 4
- 229910002588 FeOOH Inorganic materials 0.000 description 4
- LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 description 4
- 108010061075 Enterobactin Proteins 0.000 description 3
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 3
- 102000004338 Transferrin Human genes 0.000 description 3
- 108090000901 Transferrin Proteins 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 229910000396 dipotassium phosphate Inorganic materials 0.000 description 3
- SERBHKJMVBATSJ-BZSNNMDCSA-N enterobactin Chemical compound OC1=CC=CC(C(=O)N[C@@H]2C(OC[C@@H](C(=O)OC[C@@H](C(=O)OC2)NC(=O)C=2C(=C(O)C=CC=2)O)NC(=O)C=2C(=C(O)C=CC=2)O)=O)=C1O SERBHKJMVBATSJ-BZSNNMDCSA-N 0.000 description 3
- 108700041957 ferricrocin Proteins 0.000 description 3
- 239000008103 glucose Substances 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 239000012581 transferrin Substances 0.000 description 3
- YBJHBAHKTGYVGT-ZKWXMUAHSA-N (+)-Biotin Chemical compound N1C(=O)N[C@@H]2[C@H](CCCCC(=O)O)SC[C@@H]21 YBJHBAHKTGYVGT-ZKWXMUAHSA-N 0.000 description 2
- DCXYFEDJOCDNAF-UHFFFAOYSA-N Asparagine Natural products OC(=O)C(N)CC(N)=O DCXYFEDJOCDNAF-UHFFFAOYSA-N 0.000 description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 108010067157 Ferrichrome Proteins 0.000 description 2
- 108010017480 Hemosiderin Proteins 0.000 description 2
- 206010022971 Iron Deficiencies Diseases 0.000 description 2
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 2
- DCXYFEDJOCDNAF-REOHCLBHSA-N L-asparagine Chemical compound OC(=O)[C@@H](N)CC(N)=O DCXYFEDJOCDNAF-REOHCLBHSA-N 0.000 description 2
- UBQYURCVBFRUQT-UHFFFAOYSA-N N-benzoyl-Ferrioxamine B Chemical compound CC(=O)N(O)CCCCCNC(=O)CCC(=O)N(O)CCCCCNC(=O)CCC(=O)N(O)CCCCCN UBQYURCVBFRUQT-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 229960001230 asparagine Drugs 0.000 description 2
- 235000009582 asparagine Nutrition 0.000 description 2
- 239000010953 base metal Substances 0.000 description 2
- 239000001110 calcium chloride Substances 0.000 description 2
- 235000011148 calcium chloride Nutrition 0.000 description 2
- 229910001628 calcium chloride Inorganic materials 0.000 description 2
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- NHKCCADZVLTPPO-UHFFFAOYSA-N desferrioxamine E Chemical compound ON1CCCCCNC(=O)CCC(=O)N(O)CCCCCNC(=O)CCC(=O)N(O)CCCCCNC(=O)CCC1=O NHKCCADZVLTPPO-UHFFFAOYSA-N 0.000 description 2
- ZPWVASYFFYYZEW-UHFFFAOYSA-L dipotassium hydrogen phosphate Chemical compound [K+].[K+].OP([O-])([O-])=O ZPWVASYFFYYZEW-UHFFFAOYSA-L 0.000 description 2
- 235000019797 dipotassium phosphate Nutrition 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000284 extract Substances 0.000 description 2
- GGUNGDGGXMHBMJ-UHFFFAOYSA-N ferrichrome Chemical compound [Fe+3].CC(=O)N([O-])CCCC1NC(=O)CNC(=O)CNC(=O)CNC(=O)C(CCCN([O-])C(C)=O)NC(=O)C(CCCN([O-])C(C)=O)NC1=O GGUNGDGGXMHBMJ-UHFFFAOYSA-N 0.000 description 2
- 108700001348 ferrirhodin Proteins 0.000 description 2
- SEQVPEQKJMMKNO-RQCMKQRDSA-N ferrirubin Chemical compound O=C([C@@H](NC1=O)CCCN(C(\C=C(\C)CCO)=[O+]2)O3)NCC(=O)N[C@@H](CO)C(=O)N[C@@H](CO)C(=O)N[C@H]4CCCN(O5)C(\C=C(/CCO)C)=[O+][Fe-3]235(O2)[O+]=C(\C=C(\C)CCO)N2CCC[C@@H]1NC4=O SEQVPEQKJMMKNO-RQCMKQRDSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 2
- NCNCGGDMXMBVIA-UHFFFAOYSA-L iron(ii) hydroxide Chemical compound [OH-].[OH-].[Fe+2] NCNCGGDMXMBVIA-UHFFFAOYSA-L 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 230000036961 partial effect Effects 0.000 description 2
- 238000005554 pickling Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000011241 protective layer Substances 0.000 description 2
- 235000018102 proteins Nutrition 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- WLQOWIYGAYASCA-YVNMAJEFSA-N (2s)-2-[2-(1-carboxyethylamino)ethylamino]-6-[(3-carboxy-3-hydroxypropanoyl)amino]hexanoic acid Chemical compound OC(=O)C(C)NCCN[C@H](C(O)=O)CCCCNC(=O)CC(O)C(O)=O WLQOWIYGAYASCA-YVNMAJEFSA-N 0.000 description 1
- IMSODMZESSGVBE-UHFFFAOYSA-N 2-Oxazoline Chemical compound C1CN=CO1 IMSODMZESSGVBE-UHFFFAOYSA-N 0.000 description 1
- NEAQRZUHTPSBBM-UHFFFAOYSA-N 2-hydroxy-3,3-dimethyl-7-nitro-4h-isoquinolin-1-one Chemical compound C1=C([N+]([O-])=O)C=C2C(=O)N(O)C(C)(C)CC2=C1 NEAQRZUHTPSBBM-UHFFFAOYSA-N 0.000 description 1
- 241000186361 Actinobacteria <class> Species 0.000 description 1
- 229920001817 Agar Polymers 0.000 description 1
- 102000006589 Alpha-ketoglutarate dehydrogenase Human genes 0.000 description 1
- 108020004306 Alpha-ketoglutarate dehydrogenase Proteins 0.000 description 1
- 102000000546 Apoferritins Human genes 0.000 description 1
- 108010002084 Apoferritins Proteins 0.000 description 1
- 239000004475 Arginine Substances 0.000 description 1
- 241000639924 Aspergillaceae Species 0.000 description 1
- 241001277111 Aspergillus viridinutans Species 0.000 description 1
- SERBHKJMVBATSJ-UHFFFAOYSA-N Enterobactin Natural products OC1=CC=CC(C(=O)NC2C(OCC(C(=O)OCC(C(=O)OC2)NC(=O)C=2C(=C(O)C=CC=2)O)NC(=O)C=2C(=C(O)C=CC=2)O)=O)=C1O SERBHKJMVBATSJ-UHFFFAOYSA-N 0.000 description 1
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 102000003886 Glycoproteins Human genes 0.000 description 1
- 108090000288 Glycoproteins Proteins 0.000 description 1
- AHLPHDHHMVZTML-BYPYZUCNSA-N L-Ornithine Chemical compound NCCC[C@H](N)C(O)=O AHLPHDHHMVZTML-BYPYZUCNSA-N 0.000 description 1
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 description 1
- 239000004472 Lysine Substances 0.000 description 1
- VDTYHTVHFIIEIL-LURJTMIESA-N N-(2,3-dihydroxybenzoyl)-L-serine Chemical compound OC[C@@H](C(O)=O)NC(=O)C1=CC=CC(O)=C1O VDTYHTVHFIIEIL-LURJTMIESA-N 0.000 description 1
- PVOAJDXMWUGTAI-UHFFFAOYSA-N N-[3-[5,8-bis[3-[acetyl(hydroxy)amino]propyl]-11,14-bis(hydroxymethyl)-3,6,9,12,15,18-hexaoxo-1,4,7,10,13,16-hexazacyclooctadec-2-yl]propyl]-N-hydroxyacetamide Chemical compound CC(=O)N(O)CCCC1NC(=O)CNC(=O)C(CO)NC(=O)C(CO)NC(=O)C(CCCN(O)C(C)=O)NC(=O)C(CCCN(O)C(C)=O)NC1=O PVOAJDXMWUGTAI-UHFFFAOYSA-N 0.000 description 1
- AHLPHDHHMVZTML-UHFFFAOYSA-N Orn-delta-NH2 Natural products NCCCC(N)C(O)=O AHLPHDHHMVZTML-UHFFFAOYSA-N 0.000 description 1
- UTJLXEIPEHZYQJ-UHFFFAOYSA-N Ornithine Natural products OC(=O)C(C)CCCN UTJLXEIPEHZYQJ-UHFFFAOYSA-N 0.000 description 1
- 241000237981 Patella vulgata Species 0.000 description 1
- 241000237988 Patellidae Species 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 241000589517 Pseudomonas aeruginosa Species 0.000 description 1
- WLQOWIYGAYASCA-UHFFFAOYSA-N Rhizobactin Natural products OC(=O)C(C)NCCNC(C(O)=O)CCCCNC(=O)CC(O)C(O)=O WLQOWIYGAYASCA-UHFFFAOYSA-N 0.000 description 1
- 241000191982 Staphylococcus hyicus Species 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 241000218589 Streptomyces olivaceus Species 0.000 description 1
- 208000002903 Thalassemia Diseases 0.000 description 1
- 241000251539 Vertebrata <Metazoa> Species 0.000 description 1
- 241000607734 Yersinia <bacteria> Species 0.000 description 1
- UWCZXCNPPLLCQU-UHFFFAOYSA-K [Fe+3].OOO.[O-]P([O-])([O-])=O Chemical compound [Fe+3].OOO.[O-]P([O-])([O-])=O UWCZXCNPPLLCQU-UHFFFAOYSA-K 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 235000001014 amino acid Nutrition 0.000 description 1
- 229940024606 amino acid Drugs 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 230000003698 anagen phase Effects 0.000 description 1
- ODKSFYDXXFIFQN-UHFFFAOYSA-N arginine Natural products OC(=O)C(N)CCCNC(N)=N ODKSFYDXXFIFQN-UHFFFAOYSA-N 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 229960002685 biotin Drugs 0.000 description 1
- 235000020958 biotin Nutrition 0.000 description 1
- 239000011616 biotin Substances 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 229940041514 candida albicans extract Drugs 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- VOAXAOULFRTTAM-UHFFFAOYSA-N chloroform phenol Chemical compound C1(=CC=CC=C1)O.C(Cl)(Cl)Cl.C1(=CC=CC=C1)O.C1(=CC=CC=C1)O VOAXAOULFRTTAM-UHFFFAOYSA-N 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 210000000805 cytoplasm Anatomy 0.000 description 1
- 229960000958 deferoxamine Drugs 0.000 description 1
- 108010042801 desferri-ferricrocin Proteins 0.000 description 1
- MIVGUYBAQIHKPJ-UHFFFAOYSA-N desferrioxamine G Chemical compound NCCCCCN(O)C(=O)CCC(=O)NCCCCCN(O)C(=O)CCC(=O)NCCCCCN(O)C(=O)CCC(O)=O MIVGUYBAQIHKPJ-UHFFFAOYSA-N 0.000 description 1
- 238000000502 dialysis Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 108700001718 ferrichrysin Proteins 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 239000000834 fixative Substances 0.000 description 1
- 230000002538 fungal effect Effects 0.000 description 1
- 238000005246 galvanizing Methods 0.000 description 1
- 230000012010 growth Effects 0.000 description 1
- 239000003102 growth factor Substances 0.000 description 1
- 229910052595 hematite Inorganic materials 0.000 description 1
- 239000011019 hematite Substances 0.000 description 1
- 210000000087 hemolymph Anatomy 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- LDHBWEYLDHLIBQ-UHFFFAOYSA-M iron(3+);oxygen(2-);hydroxide;hydrate Chemical compound O.[OH-].[O-2].[Fe+3] LDHBWEYLDHLIBQ-UHFFFAOYSA-M 0.000 description 1
- 229910021506 iron(II) hydroxide Inorganic materials 0.000 description 1
- 239000003446 ligand Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000010297 mechanical methods and process Methods 0.000 description 1
- 230000002503 metabolic effect Effects 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 230000035772 mutation Effects 0.000 description 1
- JXJRJDNSPWNZOK-CMOCDZPBSA-N n-[3-[(2s,5s,8s,14s)-5,8-bis[3-[acetyl(hydroxy)amino]propyl]-14-(hydroxymethyl)-3,6,9,12,15,18-hexaoxo-1,4,7,10,13,16-hexazacyclooctadec-2-yl]propyl]-n-hydroxyacetamide Chemical compound CC(=O)N(O)CCC[C@@H]1NC(=O)CNC(=O)[C@H](CO)NC(=O)CNC(=O)[C@H](CCCN(O)C(C)=O)NC(=O)[C@H](CCCN(O)C(C)=O)NC1=O JXJRJDNSPWNZOK-CMOCDZPBSA-N 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 239000012074 organic phase Substances 0.000 description 1
- 229960003104 ornithine Drugs 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 230000004962 physiological condition Effects 0.000 description 1
- 229920005646 polycarboxylate Polymers 0.000 description 1
- 210000002729 polyribosome Anatomy 0.000 description 1
- 229930010796 primary metabolite Natural products 0.000 description 1
- 210000004777 protein coat Anatomy 0.000 description 1
- 238000009790 rate-determining step (RDS) Methods 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000029058 respiratory gaseous exchange Effects 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000036962 time dependent Effects 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 238000005491 wire drawing Methods 0.000 description 1
- 238000010626 work up procedure Methods 0.000 description 1
- 239000012138 yeast extract Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G5/00—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/24—Cleaning or pickling metallic material with solutions or molten salts with neutral solutions
Definitions
- a modified nutrient solution according to Zahnner [Zahnner, H.; W. Keller-Schierlein, R. Wilsonter, K. Hess-Leisinger, A. Deer: Metabolic products of microorganisms, 40th middle Sideramine from Aspergillaceae. Arch. Microbiol. 45, 1 19, (1963)] uses:
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
Abstract
L'invention concerne un agent à base de composés organiques obtenus à partir de micro-organismes, servant à dérouiller des surfaces métalliques présentant des oxydes de fer. Le dérouillage de pièces métalliques s'effectue généralement au moyen de bains de décapage renfermant des acides organiques et/ou inorganiques qui doivent répondre, en raison de la concentration utilisée, à des exigences de sécurité particulières et nécessitent un important investissement pour être éliminés, une fois leur capacité épuisée. Les produits liant le fer, pouvant être obtenus par voie biologique, agissent en général dans la plage neutre du pH, ce qui permet d'éviter l'apparition de sels liée à la neutralisation, nécessaire dans les autres cas, et par conséquent une contamination des eaux résiduaires. Il est possible d'effectuer un dérouillage au moyen de produits intracellulaires ou extracellulaires reproductibles qui présentent une affinité élevée avec les ions de fer. Le procédé de fabrication des agents mentionnés précédemment consiste à cultiver les cellules d'organismes appropriés dans un fluide adéquat de façon à les stimuler pour qu'elles produisent ces agents. Le traitement des pièces à dérouiller consiste à plonger les pièces dans cet agent ou à les revêtir avec celui-ci. L'immobilisation sur des supports facilitent la manipulation de ces agents et permet de récupérer les agents par un traitement approprié.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AU36077/95A AU3607795A (en) | 1994-09-20 | 1995-09-18 | Organically-based agent for removing rust from surfaces, production and use of said agent |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEP4433376.5 | 1994-09-20 | ||
| DE19944433376 DE4433376C1 (de) | 1994-09-20 | 1994-09-20 | Verfahren zum Entrosten von Oberflächen auf organischer Basis und Verfahren zur Herstellung des eingesetzten Mittels |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| WO1996009423A1 true WO1996009423A1 (fr) | 1996-03-28 |
| WO1996009423B1 WO1996009423B1 (fr) | 1996-05-30 |
Family
ID=6528611
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/EP1995/003670 WO1996009423A1 (fr) | 1994-09-20 | 1995-09-18 | Agent a base organique servant au derouillage de surfaces, son procede de fabrication et son utilisation |
Country Status (3)
| Country | Link |
|---|---|
| AU (1) | AU3607795A (fr) |
| DE (1) | DE4433376C1 (fr) |
| WO (1) | WO1996009423A1 (fr) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102007015085A1 (de) * | 2007-03-29 | 2008-10-02 | Asa Spezialenzyme Gmbh | Verfahren zur Entfernung von Korrosionsschichten |
| US7759113B2 (en) | 1999-04-30 | 2010-07-20 | The General Hospital Corporation | Fabrication of tissue lamina using microfabricated two-dimensional molds |
| US8173361B2 (en) | 2003-01-16 | 2012-05-08 | The General Hospital Corporation | Method of determining metabolism of a test agent |
| US8491561B2 (en) | 2002-03-25 | 2013-07-23 | The Charles Stark Draper Laboratory | Micromachined bilayer unit of engineered tissues |
| CN107557792A (zh) * | 2017-07-31 | 2018-01-09 | 常州诺丁精密机械制造有限公司 | 一种利用蓝藻对钢铁除锈的方法 |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19830848A1 (de) * | 1998-07-10 | 2000-01-13 | Daimler Chrysler Ag | Verfahren und Mittel zur Behandlung der Oberflächen von Gebrauchsgegenständen |
| DE102007008655A1 (de) | 2007-02-20 | 2008-08-21 | Henkel Ag & Co. Kgaa | Siderophor-Metall-Komplexe als Bleichkatalysatoren |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE352580A (fr) * | ||||
| US3110679A (en) * | 1959-03-17 | 1963-11-12 | Rubin Martin | Neutral composition for removal of rust |
| FR2160464A1 (fr) * | 1971-11-16 | 1973-06-29 | Kansai Paint Co Ltd | |
| FR2219984A1 (fr) * | 1973-03-01 | 1974-09-27 | Kansai Paint Co Ltd | |
| JPS59113185A (ja) * | 1982-12-17 | 1984-06-29 | Tomoji Tanaka | 無公害金属表面処理法 |
-
1994
- 1994-09-20 DE DE19944433376 patent/DE4433376C1/de not_active Expired - Fee Related
-
1995
- 1995-09-18 WO PCT/EP1995/003670 patent/WO1996009423A1/fr active Application Filing
- 1995-09-18 AU AU36077/95A patent/AU3607795A/en not_active Abandoned
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE352580A (fr) * | ||||
| US3110679A (en) * | 1959-03-17 | 1963-11-12 | Rubin Martin | Neutral composition for removal of rust |
| FR2160464A1 (fr) * | 1971-11-16 | 1973-06-29 | Kansai Paint Co Ltd | |
| FR2219984A1 (fr) * | 1973-03-01 | 1974-09-27 | Kansai Paint Co Ltd | |
| JPS59113185A (ja) * | 1982-12-17 | 1984-06-29 | Tomoji Tanaka | 無公害金属表面処理法 |
Non-Patent Citations (1)
| Title |
|---|
| CHEMICAL ABSTRACTS, vol. 101, no. 18, 29 October 1984, Columbus, Ohio, US; abstract no. 155919j, TANAKA: "Nonpolluting steel surface treatment" page 239; * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7759113B2 (en) | 1999-04-30 | 2010-07-20 | The General Hospital Corporation | Fabrication of tissue lamina using microfabricated two-dimensional molds |
| US8642336B2 (en) | 1999-04-30 | 2014-02-04 | The General Hospital Corporation | Fabrication of vascularized tissue using microfabricated two-dimensional molds |
| US8491561B2 (en) | 2002-03-25 | 2013-07-23 | The Charles Stark Draper Laboratory | Micromachined bilayer unit of engineered tissues |
| US8173361B2 (en) | 2003-01-16 | 2012-05-08 | The General Hospital Corporation | Method of determining metabolism of a test agent |
| DE102007015085A1 (de) * | 2007-03-29 | 2008-10-02 | Asa Spezialenzyme Gmbh | Verfahren zur Entfernung von Korrosionsschichten |
| CN107557792A (zh) * | 2017-07-31 | 2018-01-09 | 常州诺丁精密机械制造有限公司 | 一种利用蓝藻对钢铁除锈的方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| AU3607795A (en) | 1996-04-09 |
| DE4433376C1 (de) | 1996-04-04 |
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