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WO2008138167A1 - A method for producing coal gas - Google Patents

A method for producing coal gas Download PDF

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Publication number
WO2008138167A1
WO2008138167A1 PCT/CN2007/001547 CN2007001547W WO2008138167A1 WO 2008138167 A1 WO2008138167 A1 WO 2008138167A1 CN 2007001547 W CN2007001547 W CN 2007001547W WO 2008138167 A1 WO2008138167 A1 WO 2008138167A1
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WO
WIPO (PCT)
Prior art keywords
gas
temperature
gasifying agent
coal
heat
Prior art date
Application number
PCT/CN2007/001547
Other languages
French (fr)
Chinese (zh)
Inventor
Zhiping Xie
Original Assignee
Foshan Keda Energy Resource Machinery Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Foshan Keda Energy Resource Machinery Co., Ltd. filed Critical Foshan Keda Energy Resource Machinery Co., Ltd.
Priority to PCT/CN2007/001547 priority Critical patent/WO2008138167A1/en
Priority to AU2007353260A priority patent/AU2007353260B2/en
Priority to EP07721120.9A priority patent/EP2149595B1/en
Publication of WO2008138167A1 publication Critical patent/WO2008138167A1/en
Priority to US12/618,462 priority patent/US8029581B2/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/80—Other features with arrangements for preheating the blast or the water vapour
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0903—Feed preparation
    • C10J2300/0909—Drying
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/093—Coal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/093—Coal
    • C10J2300/0933—Coal fines for producing water gas
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/093—Coal
    • C10J2300/0936—Coal fines for producing producer gas
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0956—Air or oxygen enriched air
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0959—Oxygen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0973—Water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1861—Heat exchange between at least two process streams
    • C10J2300/1892—Heat exchange between at least two process streams with one stream being water/steam
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines

Definitions

  • the present invention relates to a method of producing coal gas, and more particularly to a method of producing coal gas from pulverized coal. Background technique
  • the process of producing coal gas using pulverized coal generally includes feeding pulverized coal, steam, air and oxygen into a gas generating furnace to cause a reaction at a high temperature to generate gas, and the generated gas is returned to the pulverized coal through a cyclone.
  • the gas is used to generate steam through the waste heat boiler, and the cleaned and cooled gas is sent to the user. Since the temperature of the gas coming out of the gas generator is very high, the steam generated after the waste heat boiler exceeds the gas production requirements, and the excess is used for other purposes; and because of the steam, air and oxygen entering the gas furnace.
  • the temperature of the gasifying agent is relatively low, usually 65 °C ⁇ 12 (TC, and the temperature of the gasifying agent needs to rise to 100 (TC ⁇ 1100 °C) during the reaction in the furnace, which is consumed during the temperature increase of the gasifying agent.
  • TC 65 °C ⁇ 12
  • the above factors all cause a relatively high coal consumption per unit of gas produced, usually at 0.3 Kg/Nm 3 ⁇ 0.4 Kg/Nm 3 or more; and the gas produced by the above conventional process has a low calorific value.
  • an object of the present invention is to provide a gas production method which not only reduces coal consumption but also increases the heat value of the generated gas.
  • the present invention provides a gas production method comprising: adding a raw material pulverized coal and a high-temperature gasifying agent to a gas generating furnace to generate a gas;
  • the hot gas is exchanged with the gasifying agent to generate a high temperature gasifying agent
  • the gas after heat exchange with the gasifying agent exchanges heat with water to produce steam, which is a component of the gasifying agent
  • the gas after heat exchange with water is further dedusted and desulfurized and then output.
  • the gas After the gas is generated and before the heat exchange with the gasifying agent, it is subjected to a thousand-type high-temperature separation treatment, and the separated pulverized coal is sent back to the gas generator.
  • the gas After the high-temperature gasification agent is produced, the gas is exchanged with the water to produce steam, and the dry coal is subjected to dry low-temperature separation treatment, and the separated pulverized coal is sent back to the gas generator.
  • the temperature of the heat exchange between the tapping gas and the gasifying agent is 50 (TC - 700 'C; the heat exchange between the gas and the water is carried out in a waste heat boiler, and the inlet temperature of the waste heat boiler is 400 ° C - 500. C.
  • the gasifying agent is air and steam, oxygen-enriched air and steam, or pure oxygen and steam.
  • the raw coal powder When initially operated, the raw coal powder is added from the lower portion of the gas generator. When the temperature of the gas generator is operating normally, the raw coal powder is fed from the upper portion of the gas generator.
  • the high temperature gasifying agent is fed from three locations of the gas generator; the first of the three positions is located at a lower portion of the gas generator, and the high temperature gasifying agent is fed in a amount of 50% - 60%; the second is located in the middle of the gas generator, the high-temperature gasifying agent is fed in an amount of 35% - 45%; the third is located in the middle of the gas generating furnace;
  • the pulverized coal separated by the cryogenic separator is sent to a gas generator together, and the high-temperature gasifying agent is fed in an amount of 5%.
  • the high temperature gasifying agent has a temperature of from 750 ° C to 850 ° C.
  • the coal gas supplied to the user has a pulverized coal content of 5 mg/Nm 3 .
  • the proportion of air, oxygen-enriched air or pure oxygen in the gasifying agent is: 50 - 80 %, and the proportion of steam in the gasifying agent is 20 - 50%.
  • the gas production method provided by the invention exchanges the gasification agent entering the furnace with the gas discharged from the furnace, so that the temperature of the gasification agent entering the furnace reaches 750 ° C ⁇ 850 ° C, so the reaction of the pulverized coal with the high temperature gasification agent
  • the calorie consumption is 20% to 30% lower than that of the normal temperature gasifying agent, and the combustible component of the gas is 20% to 30% higher than the mixed gas of the normal temperature gasifying agent.
  • the present invention heats the gas from 950 ° C to 1100 ° C of the gas furnace and 60 ° C ⁇ 10 (the gasification agent of TC exchanges heat through the heat exchanger, and the temperature of the gasification agent after heat exchange rises to 750 ° C - 850 ° C, the temperature drops to 40 (TC ⁇ 500 °C gas and then enter the waste heat boiler to produce steam, after the waste heat boiler comes out, the gas temperature drops to about 150 °C, into the Venturi dust collector and washing tower dust removal, After the final desulfurization, it is sent to the user.
  • the gasification agent of TC exchanges heat through the heat exchanger, and the temperature of the gasification agent after heat exchange rises to 750 ° C - 850 ° C, the temperature drops to 40 (TC ⁇ 500 °C gas and then enter the waste heat boiler to produce steam, after the waste heat boiler comes out, the gas temperature drops to about 150 °C, into the Venturi dust collector and washing tower dust removal, After the final desulfurization
  • the gas heat is supplied to the gasifying agent, and the temperature of the gasifying agent rises, so that the steam content increases, and the reaction speed with the coal increases, not only the coal
  • the gas generator has low coal consumption and good gas composition. More importantly, the heat in the gas is effectively recovered, and the coal consumption is reduced by 20% to 30%. Compared with the coal consumption of the prior art gas furnace using the normal temperature gasifying agent of 0.3 g/Nm 3 to 0.4 Kg/Nm 3 , the coal consumption of the mixed gas of the present invention is reduced to 0.22 g/Nm 3 to 0.25 Kg/Nm 3 0 .
  • the invention adopts two separations of high temperature and low temperature to greatly reduce the amount of pulverized coal carried by the gas, and the separated pulverized coal is reintroduced into the furnace, thereby further reducing the coal consumption of the gas generator.
  • the calorific value of the mixed gas produced by the air-steaming gasification agent is 5600 KJ/Nm 3 - 6000 KJ/Nra 3 , (1350 kcal/Nm 3 ⁇ 1450 kcal/Nm 3 ), and the coal consumption is only 0.22 Kg/Nm 3 ⁇ 0.25 Kg/Nm 3 , low coal consumption, high calorific value, high production efficiency and low cost.
  • FIG. 1 is a flow chart 1 of an embodiment of a gas generating method of the present invention. detailed description
  • the raw material pulverized coal 1 with water content ⁇ 8% is sent to the gas generator through the coal feeder. If the water content of the raw pulverized coal is higher than 8%, it needs to be dried first.
  • the raw pulverized coal 1 is generated from the gas.
  • the lower part of the furnace is fed.
  • the high temperature gasifying agent 7 having a temperature of 750 - 850 ° C is fed into the gas generating furnace from three positions. A reaction occurs in the gas generator to generate gas.
  • One of the three locations is added from the lower portion of the gas generator, the amount of addition is 50% - 60%, and the other is added from the middle of the gas generator.
  • the addition amount is from 35% to 45%, and the third enters from the circulating coal inlet of the gas generator, and the circulating coal is sent to the gas generator, which accounts for 5% of the total high-temperature gasification dose; the gas passes through a dry high temperature
  • the separator separates the pulverized coal 1 carrying the particles having a diameter larger than 10 ⁇ m, and is sent back to the gas generator as circulating coal, and then separated into a heat exchanger, and exchanges heat to the air 3 and steam 4 Composed of a gasifying agent, making The chemical is heated to 750 - 850 high temperature gasification agent 7, the temperature of the gas is 500 - 700 ° C, the temperature of the gas out of the heat exchanger is 400 - 500 ° C, and then enters a dry low temperature
  • the separator further separates all of the coal particles larger than 5
  • the air may also be oxygen-enriched air or pure oxygen;
  • the gas production process reduces the coal consumption by heating the gasification agent into the gas generator after preheating; and the raw material pulverized coal enters the gas generator from two inlets, and The gas-carrying pulverized coal is returned to the gas generator, which further reduces the coal consumption, so that the coal consumption is only 0.22 g/Nm 3 ⁇ 0.25 Kg/Nm 3 of gas, and the calorific value of the gas is increased to 600 KJ/Nm 3 gas.
  • ⁇ 6000n/Nm 3 gas (1350 kcal / Nm 3 gas ⁇ 1450kcal / Nm 3 gas).
  • the air consumption is 0.6 - 0.65 Kg / Nm 3 of gas.
  • the composition of the gas composition obtained is: H 2 : 15% - 20%; CO: 25% - 30%; C0 2 : 5 % - 8 %; N 2 : 40% - 50%; (3 ⁇ 4: 2% -3 %; 0 2 : 0.2% - 0.5%.
  • the ratio of air, oxygen-enriched air or pure oxygen in the gasifying agent is: 75 - 80%, and the proportion of steam is 20 - 25 %.
  • the parameters in this embodiment are as follows: Combination:
  • Gas specific heat is 0.33kcal/Nm 3 gas

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)
  • Industrial Gases (AREA)

Abstract

A method for producing coal gas comprises: introducing raw coal powders (1) and high temperature gasification agents (7) into a gasification furnace (a) for reacting and producing coal gas, the produced coal gas leaving the furnace and exchanging heat with gasification agents and producing high temperature gasification agents (7), the coal gas exchanging heat with water and producing steam (4) which is one part of the gasification agents, dusting, desulfurizing and outputting the coal gas. The coal gas is dry type high temperature separated before exchanging heat with the gasification agents, and coal powders (2) separated from the coal gas are returned to the gasification furnace (a). The coal gas is dry type low temperature separated after producing high temperature gasification agents (7) and before producing steam (4) by heat exchanging with water, and coal powders (5) separated from gas stream are returned to the gasifier furnace (a). The high temperature gasification agents (7) have a temperature of 750-850 °C and are conveyed to the furnace (a) from three locations. The method has a low consumption of coal, low equipment attrition, a high heat value of produced coal gas.

Description

一种煤气生产方法 技术领域  Gas production method
本发明涉及一种煤气的生产方法， 尤其涉及用粉煤生产煤气的方法。 背景技术  The present invention relates to a method of producing coal gas, and more particularly to a method of producing coal gas from pulverized coal. Background technique
利用粉煤生产煤气的工艺通常包括， 把粉煤、 蒸汽、 空气和氧气送入煤 气发生炉， 使之在在高温状态下发生反应， 产生煤气， 所产生的煤气经旋风 除尘器将粉煤返回煤气发生炉， 煤气则经过废热锅炉用于产生蒸汽， 经洗涤 冷却后的煤气送入用户。 由于从煤气发生炉出来的煤气温度非常高， 经过废 热锅炉后产生的蒸汽超出了煤气生产所需， 超出部分就会用于其它的用途； 同时由于进入煤气炉内的蒸汽、 空气和氧气组成的气化剂的温度比较低， 通 常为 65 °C ~ 12(TC， 而在炉内反应时， 气化剂温度需要升到 100(TC ~ 1100°C， 在提高气化剂温度期间就会消耗大量的反应热量。 以上因素都造成了生产的单 位煤气煤耗比较高， 通常在 0. 3 Kg/Nm3 ~ 0. 4Kg/Nm3以上； 而且以上述传统工 艺生产的煤气热值低。 发明内容 The process of producing coal gas using pulverized coal generally includes feeding pulverized coal, steam, air and oxygen into a gas generating furnace to cause a reaction at a high temperature to generate gas, and the generated gas is returned to the pulverized coal through a cyclone. In the gas generator, the gas is used to generate steam through the waste heat boiler, and the cleaned and cooled gas is sent to the user. Since the temperature of the gas coming out of the gas generator is very high, the steam generated after the waste heat boiler exceeds the gas production requirements, and the excess is used for other purposes; and because of the steam, air and oxygen entering the gas furnace. The temperature of the gasifying agent is relatively low, usually 65 °C ~ 12 (TC, and the temperature of the gasifying agent needs to rise to 100 (TC ~ 1100 °C) during the reaction in the furnace, which is consumed during the temperature increase of the gasifying agent. A large amount of heat of reaction. The above factors all cause a relatively high coal consumption per unit of gas produced, usually at 0.3 Kg/Nm 3 ~ 0.4 Kg/Nm 3 or more; and the gas produced by the above conventional process has a low calorific value.
为了解决上述问题， 本发明的目的是提供一种煤气生产方法， 不仅降低 煤耗， 而且增加所产生煤气的热值。  In order to solve the above problems, an object of the present invention is to provide a gas production method which not only reduces coal consumption but also increases the heat value of the generated gas.
为了实现上述目的， 本发明提供了一种煤气生产方法， 包括： 向煤气发生炉内加入原料粉煤和高温气化剂， 反应生成煤气；  In order to achieve the above object, the present invention provides a gas production method comprising: adding a raw material pulverized coal and a high-temperature gasifying agent to a gas generating furnace to generate a gas;
出炉煤气与气化剂进行热交换， 产生高温气化剂；  The hot gas is exchanged with the gasifying agent to generate a high temperature gasifying agent;
与气化剂热交换后的煤气与水进行热交换， 生产蒸汽， 所述蒸汽为气化剂 的组成部分；  The gas after heat exchange with the gasifying agent exchanges heat with water to produce steam, which is a component of the gasifying agent;
将与水进行热交换后的煤气进一步除尘和脱硫后输出。 在生成煤气之后、 与气化剂进行热交换之前还经过千式高温分离处理， 所 分离出的粉煤被送回煤气发生炉。 在产生高温气化剂之后、 煤气与水进行热交 换生产蒸汽之前还经过干式低温分离处理，所分离出的粉煤被送回煤气发生炉。 The gas after heat exchange with water is further dedusted and desulfurized and then output. After the gas is generated and before the heat exchange with the gasifying agent, it is subjected to a thousand-type high-temperature separation treatment, and the separated pulverized coal is sent back to the gas generator. After the high-temperature gasification agent is produced, the gas is exchanged with the water to produce steam, and the dry coal is subjected to dry low-temperature separation treatment, and the separated pulverized coal is sent back to the gas generator.
所述出炉煤气与气化剂进行热交换的温降为 50(TC - 700'C；。 所述煤气与 水进行热交换在废热锅炉中进行， 在所述废热锅炉的入口温度为 400°C - 500 。C。  The temperature of the heat exchange between the tapping gas and the gasifying agent is 50 (TC - 700 'C; the heat exchange between the gas and the water is carried out in a waste heat boiler, and the inlet temperature of the waste heat boiler is 400 ° C - 500. C.
所述气化剂为空气和蒸汽、 富氧空气和蒸汽、 或纯氧和蒸汽。  The gasifying agent is air and steam, oxygen-enriched air and steam, or pure oxygen and steam.
当初始运行时， 所述原料煤粉从所述煤气发生炉的下部加入。 当所述煤气 发生炉的温度运行正常时， 所述原料煤粉从所述煤气发生炉的上部加入。  When initially operated, the raw coal powder is added from the lower portion of the gas generator. When the temperature of the gas generator is operating normally, the raw coal powder is fed from the upper portion of the gas generator.
所述高温气化剂从所述煤气发生炉的三个位置送入；所述三个位置中第一 个位于所述煤气发生炉的下部， 所述高温气化剂送入量为 50%- 60%; 第二个位 于所述煤气发生炉的中部， 所述高温气化剂送入量为 35%- 45%; 第三个位于所 述煤气发生炉的中部； 将所述高温分离器和低温分离器分离出的粉煤一起送入 煤气发生炉， 所述高温气化剂送入量为 5%。  The high temperature gasifying agent is fed from three locations of the gas generator; the first of the three positions is located at a lower portion of the gas generator, and the high temperature gasifying agent is fed in a amount of 50% - 60%; the second is located in the middle of the gas generator, the high-temperature gasifying agent is fed in an amount of 35% - 45%; the third is located in the middle of the gas generating furnace; The pulverized coal separated by the cryogenic separator is sent to a gas generator together, and the high-temperature gasifying agent is fed in an amount of 5%.
所述高温气化剂的温度为 750°C - 850°C。  The high temperature gasifying agent has a temperature of from 750 ° C to 850 ° C.
所述供给用户的煤气的粉煤含量 5mg/Nm3。 空气、 富氧空气或纯氧在气 化剂中的比例为： 50 - 80 % , 蒸汽在气化剂中的比例为 20 - 50 %。 The coal gas supplied to the user has a pulverized coal content of 5 mg/Nm 3 . The proportion of air, oxygen-enriched air or pure oxygen in the gasifying agent is: 50 - 80 %, and the proportion of steam in the gasifying agent is 20 - 50%.
本发明提供的煤气生产方法， 使入炉的气化剂与出炉的煤气经热交换， 从而入炉的气化剂温度达到 750°C ~ 850°C , 因此粉煤与高温气化剂的反应 热量消耗比常温气化剂低 20% ~ 30%， 而且煤气的可燃成份较常温气化剂的 混合煤气高 20% ~ 30%。 具体地， 本发明将出煤气炉的 950 °C ~ 1100 °C煤气与 60°C ~ 10(TC的气化剂通过换热器进行换热， 换热后的气化剂温度上升达到 750 °C - 850°C , 温度下降至 40(TC ~ 500 °C的煤气再进入废热锅炉生产水蒸 汽， 从废热锅炉出来后煤气温度降至 150°C左右， 进入文丘里除尘器和洗涤 塔除尘， 最后脱硫后送往用户。 通过煤气和气化剂热交换， 煤气热量供给气 化剂， 气化剂温度上升导致蒸汽含量增大， 与煤的反应速度加快， 不仅使煤 气发生炉煤耗低、 煤气成分好， 更主要的是有效回收了煤气中的热量， 使煤 耗下降 20%~ 30%。与使用常温气化剂的现有技术煤气炉的煤耗 0.3 g/Nm3~ 0.4 Kg/Nm3相比， 本发明混合煤气的煤耗下降至 0.22 g/Nm3~ 0.25 Kg/Nm3 0 此外， 本发明通过采用高温、 低温两次分离， 使煤气携带的粉煤量大幅度降 低，而且分离下来的粉煤又重新入炉，因此进一步降低了煤气发生炉的煤耗。 本发明由空气加蒸汽的气化剂生产的混合煤气热值在 5600 KJ/Nm3 - 6000KJ/Nra3, ( 1350 kcal/ Nm3 ~ 1450kcal/ Nm3 ) , 煤耗仅为 0.22Kg/Nm3~ 0.25 Kg/Nm3, 煤耗低， 热值高， 生产效率高，成本低。 The gas production method provided by the invention exchanges the gasification agent entering the furnace with the gas discharged from the furnace, so that the temperature of the gasification agent entering the furnace reaches 750 ° C ~ 850 ° C, so the reaction of the pulverized coal with the high temperature gasification agent The calorie consumption is 20% to 30% lower than that of the normal temperature gasifying agent, and the combustible component of the gas is 20% to 30% higher than the mixed gas of the normal temperature gasifying agent. Specifically, the present invention heats the gas from 950 ° C to 1100 ° C of the gas furnace and 60 ° C ~ 10 (the gasification agent of TC exchanges heat through the heat exchanger, and the temperature of the gasification agent after heat exchange rises to 750 ° C - 850 ° C, the temperature drops to 40 (TC ~ 500 °C gas and then enter the waste heat boiler to produce steam, after the waste heat boiler comes out, the gas temperature drops to about 150 °C, into the Venturi dust collector and washing tower dust removal, After the final desulfurization, it is sent to the user. Through the heat exchange between the gas and the gasifying agent, the gas heat is supplied to the gasifying agent, and the temperature of the gasifying agent rises, so that the steam content increases, and the reaction speed with the coal increases, not only the coal The gas generator has low coal consumption and good gas composition. More importantly, the heat in the gas is effectively recovered, and the coal consumption is reduced by 20% to 30%. Compared with the coal consumption of the prior art gas furnace using the normal temperature gasifying agent of 0.3 g/Nm 3 to 0.4 Kg/Nm 3 , the coal consumption of the mixed gas of the present invention is reduced to 0.22 g/Nm 3 to 0.25 Kg/Nm 3 0 . The invention adopts two separations of high temperature and low temperature to greatly reduce the amount of pulverized coal carried by the gas, and the separated pulverized coal is reintroduced into the furnace, thereby further reducing the coal consumption of the gas generator. The calorific value of the mixed gas produced by the air-steaming gasification agent is 5600 KJ/Nm 3 - 6000 KJ/Nra 3 , (1350 kcal/Nm 3 ~ 1450 kcal/Nm 3 ), and the coal consumption is only 0.22 Kg/Nm 3 ~ 0.25 Kg/Nm 3 , low coal consumption, high calorific value, high production efficiency and low cost.
附图说明 DRAWINGS
图 1为本发明煤气发生方法实施例流程图一。 具体实施方式  1 is a flow chart 1 of an embodiment of a gas generating method of the present invention. detailed description
以下参考图 1具体说明本发明的实施：  The implementation of the present invention will be specifically described below with reference to FIG. 1:
将含水量< 8%的原料粉煤 1经送煤机送入煤气发生炉， 如果原料粉煤的 含水量高于 8%则需要先干燥， 在刚开始运行时， 原料粉煤 1从煤气发生炉的 下部送入， 当炉温正常时， 原料粉煤 1改从煤气发生炉的上部送入； 同时将温 度为 750 - 850°C的高温气化剂 7从三个位置加入煤气发生炉， 在所述煤气发生 炉中发生反应， 产生煤气， 所述的三个位置其中一个是从煤气发生炉的下部加 入， 加入量为 50% - 60%, 另一个是从煤气发生炉的中部加入， 加入量为 35 % -45%, 第三个从煤气发生炉的循环煤入口进入， 同时将循环煤送入煤气发 生炉， 占总高温气化剂量的 5%; 所述煤气经过一干式高温分离器， 将其中所 携带的颗粒直径大于 10 μπι的粉煤 1分离，被作为循环煤重新送回煤气发生炉， 经过分离的煤气再进入一热交换器， 将热量交换给空气 3和蒸汽 4组成的气化 剂， 使得气化剂升温成 750 - 850 高温气化剂 7, 所述煤气的温降为 500 - 700 °C， 所述煤气出所述热交换器的温度为 400 - 500°C, 再进入一干式低温分离器 进一步分离其中的全部大于 5 μπι粉煤颗粒， 且分离 0- 5μηι直径颗粒的 50%, 分离出的粉煤 5被作为循环煤重新送回煤气发生炉； 出低温分离器后煤气进入 一废热锅炉用于产生蒸汽 4， 蒸汽 4是气化剂的组成部分， 出所述废热锅炉的 煤气进入一文丘里湿式除尘器和洗涤塔中进行脱^ _和进一步除尘处理， 其中通 过一水泵保持洗液 8在文丘里湿式除尘器和洗潦塔以及沉降设备中的循环， 经 过上述湿式除尘分离 90%的颗粒小于 5 μηι粉煤， 并经过沉降设备沉降后， 粉 渣 9过滤后排出， 通过洗涤塔洗涤后的煤气 6可以输送给用户。 上述工艺中空 气还可以为富氧空气或纯氧； 上述煤气生产工艺由于使气化剂预热后进入煤气 发生炉， 减少了煤耗； 同时采用原料粉煤从两个入口进入煤气发生炉， 而且将 煤气携带的粉煤重新送回煤气发生炉， 进一步减少了煤耗， 使得煤耗仅为 0.22 g/Nm3 ~ 0.25 Kg/Nm3煤气， 同时使得煤气的热值提高, 为 600 KJ/Nm3 煤气〜 6000n/Nm3煤气 （ 1350 kcal/ Nm3煤气〜 1450kcal/ Nm3煤气） 。 具体 地， 本实施例中， 空气耗量为 0.6- 0.65 Kg/Nm3煤气。 所得到的煤气成分组 成为： H2: 15% - 20%; CO: 25% - 30%; C02: 5 % - 8 %； N2: 40% - 50%; (¾: 2% -3%; 02： 0.2% - 0.5%。 气化剂中空气、 富氧空气或纯氧的比例为： 75― 80%， 蒸汽的比例为 20 - 25 %。 本实施例中的参数有以下多种组合： The raw material pulverized coal 1 with water content < 8% is sent to the gas generator through the coal feeder. If the water content of the raw pulverized coal is higher than 8%, it needs to be dried first. At the beginning of operation, the raw pulverized coal 1 is generated from the gas. The lower part of the furnace is fed. When the furnace temperature is normal, the raw material pulverized coal 1 is sent from the upper part of the gas generating furnace; at the same time, the high temperature gasifying agent 7 having a temperature of 750 - 850 ° C is fed into the gas generating furnace from three positions. A reaction occurs in the gas generator to generate gas. One of the three locations is added from the lower portion of the gas generator, the amount of addition is 50% - 60%, and the other is added from the middle of the gas generator. The addition amount is from 35% to 45%, and the third enters from the circulating coal inlet of the gas generator, and the circulating coal is sent to the gas generator, which accounts for 5% of the total high-temperature gasification dose; the gas passes through a dry high temperature The separator separates the pulverized coal 1 carrying the particles having a diameter larger than 10 μm, and is sent back to the gas generator as circulating coal, and then separated into a heat exchanger, and exchanges heat to the air 3 and steam 4 Composed of a gasifying agent, making The chemical is heated to 750 - 850 high temperature gasification agent 7, the temperature of the gas is 500 - 700 ° C, the temperature of the gas out of the heat exchanger is 400 - 500 ° C, and then enters a dry low temperature The separator further separates all of the coal particles larger than 5 μπι, and separates 50% of the 0-5 μη diameter particles, The separated pulverized coal 5 is returned to the gas generating furnace as circulating coal; after the low temperature separator is passed, the gas enters a waste heat boiler for generating steam 4, and the steam 4 is a component of the gasifying agent, and the gas of the waste heat boiler is discharged. Entering a venturi wet scrubber and scrubber for de-treatment and further dedusting, wherein the circulation of the washing liquid 8 in the venturi wet scrubber and the washing tower and the settling device is maintained by a water pump, after the above-mentioned wet dust separation 90% of the particles are less than 5 μηι of pulverized coal, and after sedimentation by the sedimentation equipment, the slag 9 is filtered and discharged, and the gas 6 washed by the washing tower can be delivered to the user. In the above process, the air may also be oxygen-enriched air or pure oxygen; the gas production process reduces the coal consumption by heating the gasification agent into the gas generator after preheating; and the raw material pulverized coal enters the gas generator from two inlets, and The gas-carrying pulverized coal is returned to the gas generator, which further reduces the coal consumption, so that the coal consumption is only 0.22 g/Nm 3 ~ 0.25 Kg/Nm 3 of gas, and the calorific value of the gas is increased to 600 KJ/Nm 3 gas. ~ 6000n/Nm 3 gas (1350 kcal / Nm 3 gas ~ 1450kcal / Nm 3 gas). Specifically, in the present embodiment, the air consumption is 0.6 - 0.65 Kg / Nm 3 of gas. The composition of the gas composition obtained is: H 2 : 15% - 20%; CO: 25% - 30%; C0 2 : 5 % - 8 %; N 2 : 40% - 50%; (3⁄4: 2% -3 %; 0 2 : 0.2% - 0.5%. The ratio of air, oxygen-enriched air or pure oxygen in the gasifying agent is: 75 - 80%, and the proportion of steam is 20 - 25 %. The parameters in this embodiment are as follows: Combination:
气化剂预热温 换热器出口气 煤耗 Kg/Nm3 煤气热值 Π/Nm3 度。 C 体温度 °C Gasification agent preheating heat exchanger outlet gas consumption coal consumption Kg/Nm 3 gas calorific value Π / Nm 3 degrees. C body temperature °C
750 500 0.25 5600  750 500 0.25 5600
850 400 0.22 6000  850 400 0.22 6000
800 450 0.24 5800 以下以空气和蒸汽为气化剂生产 IKcal的煤气耗热计算从理论上进一步 支持本发明的实施。 800 450 0.24 5800 The calculation of the gas consumption of IKcal by using air and steam as a gasifying agent below further theoretically supports the practice of the present invention.
25°C气化剂 +25°C煤 ► 1050° 煤气+ 1050°(：蒸汽  25 ° C gasification agent +25 ° C coal ► 1050 ° gas + 1050 ° (: steam
850°C气化
Figure imgf000007_0001
850 ° C gasification
Figure imgf000007_0001
85(TC气化剂 + 950°C煤 ► 25°C煤气 + 25°C蒸汽 混合气比热： 0.33kcal/Nm3oC 85 (TC gasification agent + 950 ° C coal ► 25 ° C gas + 25 ° C steam mixture specific heat: 0.33kcal / Nm 3o C
ΔΗ! =混合气带入热量 = INm3煤气的混合气量 X 850°C χ 0.33 ΔΗ! = mixed gas with heat = INm 3 gas mixture volume X 850 ° C χ 0.33
= 0.8066 χ 850 0.33 = 5068kcal/kmol.煤气  = 0.8066 χ 850 0.33 = 5068kcal/kmol. Gas
煤耗 = 0.25kg/Nm3=5.6kg/kmol Coal consumption = 0.25kg/Nm 3 = 5.6kg/kmol
原料比热 = 0.5kal/kg°C  Specific heat of raw materials = 0.5kal/kg °C
ΔΗ, =冷煤升温热 =煤耗 X原料比热 X煤温 X原料水蒸发热  ΔΗ, = cold coal heating heat = coal consumption X raw material specific heat X coal temperature X raw material water evaporation heat
= (0.25-0.25 X 0.1) X 0.5 X (950-25) 22.4 + 0.25 0.1 χ 580 χ 22.4 = 2655.8kcal/kmol  = (0.25-0.25 X 0.1) X 0.5 X (950-25) 22.4 + 0.25 0.1 χ 580 χ 22.4 = 2655.8kcal/kmol
C+02——► C02 H°co2= 97700kcal/kmol C+0 2 ——► C0 2 H° co2 = 97700kcal/kmol
C+02/2 ► CO H°co= 29400kcal/kmol C+0 2 /2 ► CO H° co = 29400kcal/kmol
C+H20 ►CO H°co= -28300kcal/kmol C+H 2 0 ►CO H° co = -28300kcal/kmol
C02含量 7% , lkmal煤气用空气 4.55/7.19 = 0.632kcal/kmol煤气 0.632kmol空气含氧 0.132kmol， CO耗氧为 C02的一半 C0 2 content 7%, lkmal gas air 4.55/7.19 = 0.632kcal/kmol gas 0.632kmol air oxygen 0.132kmol, CO oxygen consumption is half of C0 2
△ H反 =空气生成 C02的热量 +空气生成 CO的热量 +蒸汽生成 C02的热量 = 0.07 X 97700 + [(0.132-0.07) χ 2 29400] + [0.265-2 χ (0.132-0.07)] χ (-28300) -64694.3kcal/kmol煤气 △ H inverse = heat generated by air C0 2 + heat generated by air CO + steam generates heat of C0 2 = 0.07 X 97700 + [(0.132-0.07) χ 2 29400] + [0.265-2 χ (0.132-0.07)] χ (-28300) -64694.3kcal/kmol gas
煤气比热 0.33kcal/Nm3煤气； Gas specific heat is 0.33kcal/Nm 3 gas;
lNm3煤气生成 1.04Nm3湿煤气； lNm3 gas generates 1.04Nm 3 wet gas;
ΔΗ3= 8025.5kcal/kmol 因此， 生产 lkmol煤气耗热： Q= ΔΗ2+ ΔΗ3+ ΔΗ反 ΔΗ 3 = 8025.5kcal / kmol Therefore, the production of lkmol gas is heat: Q = ΔΗ 2 + ΔΗ 3 + ΔΗ
= 5068 + (-2655.8 ) + 8025.5 + 6494.3  = 5068 + (-2655.8 ) + 8025.5 + 6494.3
= 881kcal/kmol煤气  = 881kcal/kmol gas
由计算可以看出结果近似平衡， 尚余 881kcal/kmol煤气， 可用于多生成 H 最后应说明的是： 以上实施例仅用以说明本发明的技术方案而非限制， 尽 管参照较佳实施例对本发明进行了详细说明，本领域的普通技术人员应当理解， 可以对本发明的技术方案进行修改或者等同替换， 而不脱离本发明技术方案的 精神和范围。 It can be seen from the calculation that the result is approximately balanced, and the remaining 881 kcal/kmol of gas can be used for multi-generation. Finally, the above embodiments are only used to illustrate the technical solution of the present invention and not limiting, although the present invention is described with reference to the preferred embodiment. The invention has been described in detail, and those skilled in the art will understand that the invention may be modified or equivalently substituted without departing from the spirit and scope of the invention.

Claims

权 利 要 求 书 Claim
1、 一种煤气生产方法， 其特征是， 包括：  A gas production method, characterized in that it comprises:
向煤气发生炉内加入原料粉煤和高温气化剂， 反应生成煤气；  Adding raw material pulverized coal and high-temperature gasifying agent to the gas generator to form a gas;
出炉煤气与气化剂进行热交换， 产生高温气化剂；  The hot gas is exchanged with the gasifying agent to generate a high temperature gasifying agent;
与气化剂热交换后的煤气与水进行热交换， 生产蒸汽， 所述蒸汽为气化剂 的组成部分；  The gas after heat exchange with the gasifying agent exchanges heat with water to produce steam, which is a component of the gasifying agent;
将与水进行热交换后的煤气进一步除尘和脱硫后输出。  The gas after heat exchange with water is further dedusted and desulfurized and then output.
2、 根据权利要求 1所述的煤气生产方法， 其中， 在生成煤气之后、 与气 化剂进行热交换之前还经过干式高温分离处理， 所分离出的粉煤被送回煤气发 生炉。  The gas producing method according to claim 1, wherein the separated pulverized coal is returned to the gas generating furnace after the gas is generated and subjected to dry high-temperature separation treatment before heat exchange with the gasifying agent.
3、 才艮据权利要求 1所述的煤气生产方法， 其中， 在产生高温气化剂之后、 煤气与水进行热交换生产蒸汽之前还经过干式低温分离处理， 所分离出的粉煤 被送回煤气发生炉。  3. The method for producing a gas according to claim 1, wherein after the high-temperature gasifying agent is produced, the gas and the water are subjected to heat exchange to produce steam, and then subjected to dry low-temperature separation treatment, and the separated pulverized coal is sent. Go back to the gas generator.
4、 根据权利要求 1所述的煤气生产方法， 其中， 所述出炉煤气与气化剂 进行热交换的温降为 500°C - 700 ° ( 。  The gas production method according to claim 1, wherein the temperature at which the outlet gas and the gasifying agent exchange heat is 500 ° C - 700 ° (.
5、 根据权利要求 1所述的煤气生产方法， 其中， 所述煤气与水进行热交 换在废热锅炉中进行， 在所述废热锅炉的入口温度为 400 °C - 500 °C。  The gas production method according to claim 1, wherein the gas and water are heat-exchanged in a waste heat boiler, and an inlet temperature of the waste heat boiler is 400 °C - 500 °C.
6、 根据权利要求 1所述的煤气生产方法， 其中， 所述气化剂为空气和蒸 汽、 富氧空气和蒸汽、 或纯氧和蒸汽。  The gas producing method according to claim 1, wherein the gasifying agent is air and steam, oxygen-enriched air and steam, or pure oxygen and steam.
7、 根据权利要求 1所述的煤气生产方法， 其中， 所述原料煤粉从所述煤 气发生炉的下部加入。  The gas producing method according to claim 1, wherein the raw coal powder is added from a lower portion of the coal gas generating furnace.
8、 根据权利要求 1所述的煤气生产方法， 其中， 所述原料煤粉从所述煤 气发生炉的上部加入。  The gas producing method according to claim 1, wherein the raw coal powder is fed from an upper portion of the coal gas generating furnace.
9、 根据权利要求 1 - 8任一所述的煤气生产方法， 其中， 所述高温气化剂 从所述煤气发生炉的三个位置送入； 所述三个位置中第一个位于所述煤气发生 炉的下部， 所述高温气化剂送入量为 50%- 60%; 第二个位于所述煤气发生炉的 中部， 所述高温气化剂送入量为 35%-45%; 第三个位于所述煤气发生炉的中部; 所述高温气化剂送入量为 5%。 The gas production method according to any one of claims 1 to 8, wherein said high-temperature gasifying agent is fed from three positions of said gas generating furnace; and said first one of said three positions is said In the lower part of the gas generator, the high-temperature gasifying agent is fed in an amount of 50% - 60%; the second is located in the gas generating furnace In the middle portion, the high-temperature gasifying agent is fed in an amount of 35% to 45%; the third portion is located in the middle portion of the gas generating furnace; and the high-temperature gasifying agent is fed in a amount of 5%.
10、 根据权利要求 1 -8任一项所述的煤气生产方法， 其中， 所述高温气 化剂的温度为 750°C - 850°C。  The gas production method according to any one of claims 1 to 8, wherein the high temperature gasifying agent has a temperature of from 750 °C to 850 °C.
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